Aluminium sulfate (CAS 10043-01-3): storage and disposal
Hydrated aluminium sulfate is the white crystalline stock of teaching labs and, under the name alum, of histology stores that use it in staining solutions. It is classified as causing serious eye damage and as possibly corrosive to metals. Neither warning sounds dramatic on a bottle, but the eye hazard is the one most likely to cause a real injury at the bench.
- CAS number
- 10043-01-3
- Form
- Solid
- Storage class
- General
- Signal word
- Danger
- Usual EWC code
- 16 05 06*
Corrosive
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
A technician checking this shelf should look at what the bottle stands on and what closes it. With a classification as possibly corrosive to metals, a bare metal shelf or a metal-capped bottle will eventually show corrosion, so use plastic caps and a tray. Because the eye hazard is serious, keep the jar low and not at head height, particularly in a school prep room with a step stool. Histology stores should file it with other mordant salts and label any stain made from it separately with a date. It needs no special cabinet beyond a dry shelf, and the date received belongs on the label.
How to tell it has deteriorated
Look at the condition of the container and label first. The hydrate crystals can dry out and dust over with a white powder in a warm room, or take up damp and cake into a hard lump in a humid one, so a solid that has fused to the base of the jar has been stored badly. Rust-coloured staining on a metal cap, a corroded thread and a stained shelf all fit the metal-corrosion warning. A label with a faded name or no date is just as important. Aluminium sulfate does not give dramatic signs of age beyond caking and surface change.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
The code carries the setting. A laboratory pack uses 16 05 06*, discarded inorganic chemical outside a laboratory pack uses 16 05 07*, and a human healthcare setting such as a hospital histology lab uses 18 01 06*. It counts as a hazardous waste on its classification, so staining solutions made from it are described separately from the solid, with volumes. It must never go into a drain or the ordinary bin, however white and plain the crystals look. The transport classification must be confirmed for the specific waste and its form. UN 3264 is an entry for corrosive inorganic acidic liquids, not the solid aluminium sulfate described here. Keep it in a plastic-lined, tightly closed container on a tray, describe any caking, and request a specialist collection.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: hydrate.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H290 May be corrosive to metals.
- H318 Causes serious eye damage.
Precautionary statements
- P234 Keep only in original packaging.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P390 Absorb spillage to prevent material damage.
- P406 Store in corrosive resistant container with a resistant inner liner.
Substance as classified, dilutions may differ.
Questions
Why is aluminium sulfate hazardous waste when it looks like plain alum?
It is classified as causing serious eye damage and as possibly corrosive to metals, so it is handled as hazardous waste. Describe it accurately and arrange a specialist collection.
What should happen to leftover histology staining solution made from alum?
Never pour it away. Collect it in a labelled container with the volume and date, and describe it separately from the solid when you request a collection.
Why does the jar cap show rust?
The classification says it may be corrosive to metals, so a metal cap or shelf can corrode in time. Move the jar onto a tray and record the corrosion for the collector.
Which waste code do we give in a hospital?
A human healthcare setting uses 18 01 06*. A laboratory pack uses 16 05 06*, and discarded inorganic stock outside a pack uses 16 05 07*.
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