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Chemical collection and stock control for UK schools, universities and hospitals

Ammonium iron(III) sulfate (CAS 10138-04-2): storage and disposal

Ferric ammonium alum is a pale crystalline solid kept in school and college stores, university teaching labs and histology rooms, where it serves as a mordant. It is classified with a Danger signal word because of serious eye damage, alongside harmful if swallowed and skin and respiratory irritation. Whether the stock is crystals or a made-up working solution, and which setting holds it, decide how it is described and coded for collection.

CAS number
10138-04-2
Form
Solid
Storage class
General
Signal word
Danger
Usual EWC code
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

Before anything else, look at the crystals through the glass: a dry, free-flowing bottle with a sound cap is the one you can leave alone. This is general class stock, so a dry, labelled, well organised store suits it, dated on arrival. Because it is classified as causing serious eye damage, handle it with the eyes in mind and keep it clear of food grade supplies. On a histology bench the working mordant solution gets its own label, name and date, and is not shelved as if it were the crystals. School and college stores usually hold the dodecahydrate, and a bottle left open takes up moisture from the room.

How to tell it has deteriorated

On the shelf, the first thing you see in good stock is pale violet crystals. A dull, powdery or yellow-brown surface means the crystals have changed, and damp, clumped stock or a crusted cap points to moisture getting past the seal. Solutions that have been made up for histology work can darken or throw a brown deposit as they age, and a mordant bottle with no date is as much a concern as one that looks wrong. General checks apply as well: a faded label and no record of when it arrived. Altered stock is still chemical waste, so keep it in its own container and label it. Do not top up a good bottle with it.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Waste code 16 05 06* covers this item in a lab pack, and in a hospital histology department the healthcare entry 18 01 06* is the one that fits. Because the stock is classified as hazardous waste, the carrier will want a consignment note, which the collection team prepares from your description. The awkward part is usually the mix of forms: tubs of crystals alongside half-used mordant solution in unlabelled bottles. List each separately, with the strength of any solution if you know it. Nothing goes into a sink, a drain, a general waste bin or a skip, and no one should try to treat a solution before it leaves.

Waste codes and transport details for Ammonium iron(III) sulfate
EWC code, laboratory chemicals16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Hazardous wasteYes

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: dodecahydrate, histology mordant.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H315 Causes skin irritation.
  • H318 Causes serious eye damage.
  • H335 May cause respiratory irritation.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P317 Get medical help.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Which waste code do we use for ferric ammonium alum?

It depends on the setting. 16 05 06* is the usual entry in a lab pack, 16 05 07* applies to a discarded inorganic chemical outside a laboratory pack, and 18 01 06* applies in human healthcare. Give the setting when you ask for a quote.

Is a made-up mordant solution as hazardous as the crystals?

Not necessarily, and a dilute solution should not be assumed to carry the same hazards as the pure solid. It is still collected as chemical waste. Describe it as a solution, give its strength if you know it, and do not pour it away.

Where should the histology stock sit?

In a dry, labelled store, away from food and drink areas, with each bottle dated. Crystals and working solutions should be shelved and labelled separately, so no one mistakes one for the other. It is general class stock, not an acid or oxidiser.

What should we do with an old bottle that has gone yellow-brown and powdery?

Leave it sealed, label it with its condition and date if known, and put it forward for collection. It is described as the same substance. Do not mix it into fresh stock or try to restore it.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula FeH4NO8S2. EC number 233-382-4.

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