Barium carbonate (CAS 513-77-9): storage and disposal
Barium carbonate is a fine white powder held in school, college and university stores, classified as harmful if swallowed and harmful if inhaled, with UN number 1564. It is treated as hazardous waste. Although it is a general class salt on the shelf, it is a barium compound, and in older stores it is often kept beside less hazardous carbonates in tubs that all look alike.
- CAS number
- 513-77-9
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Fine powder is the thing to plan for. Because the classification includes harm on inhalation, a tub that sheds dust when opened is a problem, so keep the lid tight and the container clean on the outside. It is general class stock, so a dry, labelled, well organised store suits it, dated on arrival, away from food grade supplies and clearly separate from the calcium and magnesium carbonates it resembles. Acids dissolve the powder into soluble barium salts, so do not shelve it in or beside the acid store. Where a stock record is kept for barium compounds, it belongs on that list.
How to tell it has deteriorated
The powder is stable, so what happens is mostly about the tub. Caking or clumping points to damp, white dust around the lid shows a poor seal, and a faded label can leave an unknown carbonate with a barium compound's classification and no one aware of it. A missing date of receipt is common in old school stores. Cracked tubs and split bags leak a fine dust, which settles on the shelf below. Stock that has clumped is still barium carbonate and keeps its classification. Set any tub with a worn or doubtful label aside and mark it clearly, rather than returning it to the shelf.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Mistaken identity is the awkward problem here. A tub labelled only as a carbonate in an old store can be barium carbonate, so each one should be read, named and recorded before it goes. It is hazardous waste, collected under 16 05 06* in a lab pack or 16 05 07* outside one. Fine powder escapes from loosely closed tubs, so keep lids on and do not tip contents into another container. It must not go into a sink, a drain, general waste or a skip, and no one should try to treat it first. Record the form and the approximate amount in each tub.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: solid.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H332 Harmful if inhaled.
Precautionary statements
- P264 Wash hands and exposed skin thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P301+P317 IF SWALLOWED: Get medical help.
- P330 Rinse mouth.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P271 Use only outdoors or in a well-ventilated area.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P317 Get medical help.
Substance as classified, dilutions may differ.
Questions
Can barium carbonate go in with other carbonates?
No. It is classified as harmful if swallowed or inhaled and treated as hazardous waste, while some neighbouring carbonates are not. Keep it in its own labelled tub and record it separately so it is not mistaken for calcium or magnesium carbonate.
Why should it be kept away from acids?
Acids dissolve barium carbonate into soluble barium salts, which changes the stock into something different. Keep it out of the corrosive store and off shelves under or beside acid bottles.
What do we do with a tub whose label has worn away?
Leave it sealed, do not open it to look, and mark it as unidentified with the date. Tell the collection team what you know of its history and where it was found. It will be described as unknown.
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