Barium sulfate (CAS 7727-43-7): storage and disposal
Barium sulfate is a dense white solid that turns up in two very different places: as a laboratory powder in school, college and university stores, and as radiography contrast stock in pharmacies. It is not normally classified as hazardous, yet it remains a chemical waste that needs an accurate description. Holders must work out first which of the two they are dealing with.
- CAS number
- 7727-43-7
- Form
- Solid
- Storage class
- General
- Usual EWC code, laboratory stock
- 16 05 09
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Radiography contrast is the item that gets mislaid. Pharmacy tubs and sachets are held with medicines and follow the pharmacy's own stock control, with expiry dates checked as for any other product. The laboratory powder belongs on a general shelf in a dry, labelled store, dated on arrival and kept away from food grade supplies. Because the powder is very fine and dense, a loose lid lets it spread as white dust on the shelf and over neighbouring bottles. In a school prep room it often sits next to the barium chloride used for sulfate tests, and the two bottles should be clearly different on the label.
How to tell it has deteriorated
The powder itself changes very little. A tub that was fine and free-flowing years ago looks the same now, so the container is the thing to read. White dust around a lid shows a poor seal, clumping means damp has got in, and a faded label or no date of receipt are the usual faults. Contrast products are different because they have printed expiry dates, and sachets or tubs that are split, swollen or past their date should be put aside with their packaging. In a school store the real risk is confusion with barium chloride from a smudged label, not any visible change.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Contrast stock changes the description. A hospital pharmacy should check with its responsible pharmacist whether medicines arrangements apply, because out-of-date contrast products are not listed like loose laboratory powder. The usual entry for laboratory powder is 16 05 09, the healthcare chemical entry is 18 01 07 and a licensed medicinal contrast product generally belongs under the medicines entry 18 01 09. None of these is a hazardous waste entry, though the producer classifies the waste. It remains chemical waste and must be described accurately. It must not go into a sink, a drain, general waste or a skip, and nobody should try to treat it first. Give each container's form as powder or contrast product, and keep original packaging on contrast items with the expiry date visible.
| Usual EWC code, laboratory stock | 16 05 09 |
|---|---|
| Human healthcare setting | 18 01 07 |
| Usually classed as hazardous waste | No |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: solid, radiography contrast.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Questions
Is barium sulfate classified as hazardous?
It is not normally classified as hazardous. It is still a chemical waste, so it needs an accurate description and specialist collection. Keep it clearly labelled and apart from soluble barium salts such as the chloride.
Do out-of-date contrast products go in a lab collection?
They are described as medicinal contrast products, with expiry dates noted. A pharmacy should speak to its responsible pharmacist first, to confirm whether its own medicines arrangements apply before the stock joins any collection.
How do we avoid mixing it up with barium chloride?
Give each its own clear, dated label, shelve them apart and record both in the stock list. The two salts are both white powders, and a smudged label is the usual cause of confusion in school stores.
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