Bis-GMA (CAS 1565-94-2): storage and disposal
Composite fillings and resin cements in a dental practice are built from monomers such as Bis-GMA, which is held as a very thick liquid, usually as a component of a kit or a resin bottle. It is classified as causing skin and serious eye irritation, as possibly causing an allergic skin reaction, and as a respiratory irritant.
- CAS number
- 1565-94-2
- Form
- Liquid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
The thing that sets this one apart from a thin liquid is how slowly it moves. A thick resin clings to bottle threads and drips from the lip, so keep each container upright in a small tray that catches runs. Light-activated dental resins should be kept away from the curing lamp and from strong daylight, so a drawer or closed cupboard is better than a windowsill. Keep it apart from adhesives, etchants and cements with similar bottles, because the labels are often small. Because it may cause an allergic skin reaction, anyone wiping a sticky bottle should use appropriate gloves. Record the date of receipt on the container, and keep the surgery stock list up to date.
How to tell it has deteriorated
A thick, clear to pale resin that still moves slowly is normal for this component. What does not look right is a bottle in which the resin has set, formed a skin or hard lumps, or become stiff and cloudy where it was clear. Sticky residue round the cap, a cap that has set fast to the neck, resin smeared on the outside and a label stuck down by drips are the usual visible clues in a surgery. A bottle that has become warm to the touch, or has changed shape, should not be opened. No other change is described for this substance, so use the label date and the container to judge.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
Avoid trying to empty a bottle of thick resin to make it easier to pack. What matters is what it is and how it looks: say it is a dental resin component, note whether the contents are still liquid or have set, and give the size of the container. Surgeries with 18 01 06* in the code list for a human healthcare setting should confirm that against the product label, while a general lab entry is 16 05 06*. Do not scrape resin out, cure it under a lamp, or put it in clinical waste or the general bin. A registered carrier packs it with compatible organic items.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: dental resin component.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H315 Causes skin irritation.
- H317 May cause an allergic skin reaction.
- H319 Causes serious eye irritation.
- H335 May cause respiratory irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P271 Use only outdoors or in a well-ventilated area.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Can we cure leftover resin under the lamp and bin it?
No. Curing unwanted resin is a way of treating it and is not acceptable. Keep it in its container, labelled, and arrange specialist collection. If it has already set in the bottle, say so on the list.
Why does the cap on our resin bottle stick?
Thick resin creeps into the thread and sets there over time, gluing the cap on. It is a sign the bottle has been opened with a dirty neck. Do not force it. List the bottle with that description.
Where is it best stored in a surgery?
Upright in a tray, in a closed cupboard or drawer away from the curing lamp and daylight, and away from similar adhesive and cement bottles. Date it on arrival and record it in the stock list.
How is Bis-GMA classified?
It is classified as causing skin irritation, serious eye irritation and respiratory irritation, and as possibly causing an allergic skin reaction. Handle sticky bottles with care, and describe the resin accurately when you enquire about collection.
Related chemicals
Search the chemical database- 1,1,1-TrichloroethaneCAS 71-55-6General
- 1-NaphtholCAS 90-15-3General
- 2-NaphtholCAS 135-19-3General
- 3,3',5,5'-TetramethylbenzidineCAS 54827-17-7General
- 4-NitrophenolCAS 100-02-7General
- AcetophenoneCAS 98-86-2General