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Chemical collection and stock control for UK schools, universities and hospitals

Bismuth (CAS 7440-69-9): storage and disposal

Bismuth is held as a heavy lump in school, college and university stores. It is not normally classified as hazardous, but it remains a chemical waste that needs an accurate description. The surface colours of the metal often raise questions, and none of them is a sign that the lump has gone off.

CAS number
7440-69-9
Form
Solid
Storage class
General
Usual EWC code, laboratory stock
16 05 09

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

A lump of bismuth is usually kept in a small jar or a labelled box, and the main job of the container is to keep the label with the metal. A dry, labelled, well organised general store is suitable, dated on arrival. Metal lumps are heavy for their size, so keep them on a low shelf in a box that will not split under the weight and not in a thin card carton. Separate bismuth from food grade supplies. As a plain metal it needs no special separation beyond keeping jars of different metals clearly labelled.

How to tell it has deteriorated

Lumps of this metal often show a pinkish tint and a rainbow, iridescent skin where an oxide film has formed, and that is the ordinary look of the metal, not a sign of trouble. The metal is brittle and can chip, leaving sharp flakes in the bottom of a jar. Look at the container instead: a faded label, a cracked jar, a lid that has seized, a box that has split under the weight and a missing date of receipt. Anything damp, stained or mixed with other material should be recorded as contaminated rather than clean bismuth.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Unwanted bismuth must not be melted down, washed away or put in the bin, and it must not go into a sink, a drain, a general bin or a skip. It is not normally classified as hazardous, so 16 05 09 is the usual entry, though the producer classifies the waste, and a waste transfer note applies, but it stays a chemical waste and is described as one. Specialist collection is the only route. Record the form, the approximate weight and the condition of the container, and say whether the lump is whole or in pieces.

Waste codes for Bismuth
Usual EWC code, laboratory stock16 05 09
Usually classed as hazardous wasteNo

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: lump.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Questions

Why has our bismuth lump got a rainbow surface?

A thin oxide film on the surface gives bismuth its iridescent colours, and a pinkish tint is normal for the metal. It does not mean the lump has gone off and does not change how it is described for collection.

Is bismuth classed as hazardous waste?

It is not normally classified as hazardous, so the usual code has no asterisk. It is still a chemical waste, so it needs an accurate description and specialist collection, and it must not be thrown away with ordinary school waste.

Can bismuth be stored with other metals?

Yes, on a dry shelf with each piece in a labelled container. Heavy lumps should sit low and in a sturdy box. Keep them away from damp and food grade supplies, and keep the date of receipt on the label.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Bi. EC number 231-177-4.

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