Caffeine (CAS 58-08-2): storage and disposal
Caffeine looks like the most ordinary chemical in the store, a white crystalline powder in a school, college, university or pharmacy cupboard. It is classified as harmful if swallowed, and that is why it should not sit near food or drinks. Stock is often held as the monohydrate, bought for extraction and analysis work, and usually outlasts the practical it was ordered for.
- CAS number
- 58-08-2
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Because caffeine is familiar from tea and coffee, the main risk on a shelf is that someone treats it as a food ingredient. It is classified as harmful if swallowed, so keep it in a dry, labelled store, well away from staff room supplies and any food grade stock. A pharmacy holder keeps it with its other raw materials, with a stock record, and a school prep room should keep it out of reach of pupils. Date it on arrival, and separate it from food grade supplies even where the jar is small. The jar should never be shared with a kitchen or staff area.
How to tell it has deteriorated
Few visible signs of age show in the powder itself. Look at the container: a split label, a cracked jar, damp that has made the powder clump, and dusting around the cap. The monohydrate can change slightly with the dryness of the room, so a jar that looks different from a fresh one is not unusual and should be judged by its label and seal, not appearance. A jar with no date or no clear name is the real problem. Record what you see, and do not open a caked jar to loosen the powder.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Waste code 16 05 06* is the entry for a laboratory chemical in a lab pack, 16 05 08* applies where it counts as discarded organic chemical outside a lab pack, and a pharmacy or healthcare holder uses 18 01 06*. The jar goes by specialist collection with other solid organic chemicals and is not food waste, however familiar it looks. It must not be put in a drain, general waste or a skip, and no one should try to dissolve it first. Record the label wording, the form and the approximate quantity before asking for a collection.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: solid.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
Precautionary statements
- P264 Wash hands and exposed skin thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P301+P317 IF SWALLOWED: Get medical help.
- P330 Rinse mouth.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why is caffeine treated as hazardous waste?
It is classified as harmful if swallowed, and a laboratory or pharmacy jar of the pure powder is a chemical, not a food product. It goes by specialist collection and is described accurately, even where the quantity is small.
Can a pharmacy treat expired caffeine as ordinary pharmaceutical waste?
Healthcare holders use the code 18 01 06* where the stock is hazardous, but the right classification depends on what the stock actually is. Describe it as the raw chemical it is and ask for advice if it is a made-up product.
Our jar says monohydrate and has clumped. Is it still collectable?
Yes. Clumping shows the powder has taken in or lost moisture, which is not unusual for a hydrate. Keep it closed in its container, record the label and the condition, and request collection as normal.
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