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Chemical collection and stock control for UK schools, universities and hospitals

Calcium gluconate (CAS 299-28-5): storage and disposal

Calcium gluconate is held in university labs and hospital pharmacies, both as the solid and as ready-made products such as infusion strength preparations and gel. It is not normally classified as hazardous, but it is still a chemical waste that has to be described accurately. For most holders the deciding point is whether the item is a laboratory chemical or a medicinal product that has passed its date.

CAS number
299-28-5
Form
Solid
Storage class
General
Usual EWC code, laboratory stock
16 05 09

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Lab stock and pharmacy stock are kept apart. In a university lab where hydrofluoric acid is used, tubes of gel sit in the first aid kit and should be checked against their expiry date, with the powder, if held, on a general shelf in a dry, labelled store. In a pharmacy cupboard, infusion strength preparations stay with other medicines and follow the pharmacy's own stock control. Date solids on arrival and keep them away from food grade supplies. A gel tube that has been squeezed, split or left in a warm cupboard should be labelled as such and kept in its original packaging.

How to tell it has deteriorated

The solid gives few visible signs of ageing, so the container tells the story: caking from damp, a faded label or no date of receipt. Gel is different, and the first thing to check is the packaging. Look for split or leaking tubes, crust around the cap, a tube that has been squeezed flat, an expiry date that has passed and a label that cannot be read. Infusion strength preparations are checked against their printed expiry. If a product is past its date, or the packaging is damaged, put it aside with the record of what it was and when it arrived.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

It leaves the site through specialist collection, not through a sink, a drain or the general waste bin, and nobody should try to treat it first. The waste code 16 05 09 usually fits the laboratory solid, while a healthcare holder would normally use 18 01 09 for a medicine, though the producer classifies the waste. Hospital pharmacies should check with the responsible pharmacist whether their own medicines arrangements apply before a product goes into a collection. Describe the form of each item as powder, gel or ready-made preparation, keep original packaging on, and note the expiry date where there is one, because medicinal products that are out of date are listed differently from loose chemical.

Waste codes for Calcium gluconate
Usual EWC code, laboratory stock16 05 09
Human healthcare setting18 01 09
Usually classed as hazardous wasteNo

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: infusion strength preparations, gel.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Questions

Is out-of-date calcium gluconate gel treated as chemical waste?

It is described by what it is: a gel product, with its expiry date noted. The solid is not normally classed as hazardous, but gel in tubes still goes through specialist collection. Pharmacy holders should check their own medicines arrangements first.

Where should calcium gluconate gel be kept in a lab?

With the first aid supplies near wherever hydrofluoric acid is used, where it can be reached quickly. It is first aid only: anyone exposed to hydrofluoric acid also needs immediate emergency medical attention. Check the expiry date on each tube and replace any that are split, squeezed flat or past their date.

Does the solid go off?

It gives few visible signs. Look for caking from damp, a faded label or a missing date. If the container is damaged or undated, put it forward for collection rather than keeping it indefinitely.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C12H22CaO14. EC number 206-075-8.

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