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Chemical collection and stock control for UK schools, universities and hospitals

Calcium sulfate (CAS 7778-18-9): storage and disposal

Calcium sulfate turns up in school, college and university stores as the dihydrate and as plaster, usually in a paper sack, a tub or a bottle that has been refilled over several terms. It is not normally classified as hazardous, yet it remains a chemical waste that needs an accurate description. The form matters most: dihydrate sits quietly, while plaster behaves very differently once water reaches it.

CAS number
7778-18-9
Form
Solid
Storage class
General
Usual EWC code, laboratory stock
16 05 09

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Plaster arrives in a paper sack or a thin tub, and neither keeps damp out for long. Once a sack has been opened and folded over, the plaster at the top starts taking moisture from the air and stiffens into lumps, and a bag stored near a tap or on a floor that gets mopped can set solid. Move it into a rigid, tight lidded container, separate from the dihydrate, and label both. Keep the pair on a high, dry shelf in a general store, dated on arrival, and apart from food grade supplies. School prep rooms often hold several part-used tubs from different suppliers, so combine nothing and record each by its own label.

How to tell it has deteriorated

Dihydrate looks the same year after year: a fine white powder or small crystals. Plaster is the one that changes. A sack that feels stiff, rattles or has hard nodules inside has taken in water, and powder that no longer runs freely will not behave as a fresh batch. A fully set block in the bottom of a tub is the extreme case. Split paper, a lid stuck down with white crust and a label that has lifted from a damp surface all point to storage that was too humid. Check the date of receipt as well, since undated tubs from earlier years are the usual find.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Plaster sets hard when it meets water, which is why this stock must not go down a sink or drain, where it can block pipework. It must not go into general waste or a skip either, and nobody should try to treat it first. Collection is by the specialist route, and waste code 16 05 09 is the usual entry, though the producer classifies the waste. When you describe the stock, say which form each container holds, whether the plaster has already set, and how much is left. A set block in a tub is described as set plaster, not as loose powder. Dihydrate and plaster can travel in the same lab pack if their containers are sound and closed.

Waste codes for Calcium sulfate
Usual EWC code, laboratory stock16 05 09
Usually classed as hazardous wasteNo

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: dihydrate, plaster.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Questions

Can set or lumpy plaster still be collected?

Yes. Lumps and set blocks are collected like loose powder. Describe the condition on the label, keep it in its original container with the lid on, and do not try to break it up or dissolve it beforehand.

Is calcium sulfate classed as hazardous waste?

It is not normally classified as hazardous. It remains a chemical waste, so it still needs to be described accurately and collected by the specialist route. Check your own supplier information for the product you actually hold.

Why does our plaster go lumpy in the tub?

Plaster takes moisture from the air, and once a tub or sack has been opened the damp gets in. A tight lid and a dry shelf slow the process. Tubs that have already stiffened are best put forward for collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula CaO4S. EC number 231-900-3.

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