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Chemical collection and stock control for UK schools, universities and hospitals

Carbon dioxide (CAS 124-38-9): storage and disposal

Carbon dioxide is held in cylinders in schools, colleges, universities, pathology, clinics and veterinary practices, and in the small sparklet bulbs common in school demonstrations. It is a gas under pressure that may explode if heated, and a leak in a closed room can build up to harmful levels and cause asphyxiation, as the gas is heavier than air. Nothing visibly changes in the gas with age, so handling comes down to the container: whose it is, whether it has been used, and how far it can be kept from heat.

CAS number
124-38-9
Form
Gas
Storage class
General
Signal word
Warning
Usual EWC code
16 05 05
  • Gas under pressure pictogramGas under pressure

This chemical is a manual enquiry

This is a gas held under pressure, liquefied or in solid or cryogenic form. Cylinders and dewars are usually returned to the supplier or handled separately, and they do not go into a laboratory pack.

Held as a compressed or liquefied gas in a pressure container.

It cannot be priced through a form. Please do not open or move it. Call us or send an enquiry and we will talk through the next step, which depends on what it is. Keep following your own procedures for controlled drugs, radioactive materials, gases and asbestos.

What to do this week

  1. Leave it where it is. If it looks old, crystalline or damaged, do not open or move it and keep people away from the shelf. If there is immediate danger, such as a leak, fumes or a fire, leave the area and call 999.
  2. Write down the label wording, the rough age and where it is stored, from a safe distance.
  3. Send us those details, and a photo if you can take one without touching it.

Safe storage in a school or lab

A tall supplier cylinder and a box of small sparklet bulbs are the two forms found, and they need quite different attention. The cylinder stands upright and is chained or held in a stand, as it would be if feeding a pathology incubator, well clear of heaters and direct sun. Bulbs are more easily lost: loose in a drawer in the prep room, in a box beside the old demonstration kit, or left on a warm windowsill, where heat can raise the pressure inside. Keep them in their box, in a cool and labelled place, and keep the box dry so the thin steel does not rust. Never pierce a bulb or a cylinder valve to get rid of the contents, however few remain.

How to tell it has deteriorated

Rust on a small steel bulb is usually what a technician will see first, particularly in an old box kept somewhere damp. Rust weakens thin metal, and a badly rusted bulb should be left alone and recorded. Carbon dioxide itself shows nothing with age, so the gas is not the issue. A bulb with a pierced seal has been used and an unpierced one has not, although looks alone do not prove it is empty. Cylinders show their age through a worn supplier label, dents, damage to the valve or base rust. A hiss from a fitting suggests a leak, which can build up in a closed room, so leave the room, keep others out and call the owner or your site contact. Frost on a valve may also mean a leak of the cold gas.

How it is disposed of

This does not go through our standard collection route. It is arranged by manual enquiry, and never goes down the drain or into general waste.

It leaves by returning to whoever owns it, in the case of most cylinders, as these normally stay the supplier's property. Bulbs are less clear, and this site does not quote for either form online, since pressure containers are kept out of lab packs. Send a manual enquiry listing how many bulbs there are, whether any are rusted, and for cylinders the size, label wording and location. A store assessment is recommended where a large or mixed quantity has built up. Keep the items in place, upright and away from heat, until advice arrives. Do not puncture or vent anything to make it easier. Never put any of it in a general waste bin or skip, whether full or apparently empty.

Waste codes for Carbon dioxide
Usual EWC code16 05 05
Usually classed as hazardous wasteNo

Gases in pressure containers are assessed by manual enquiry, usually with return to the cylinder owner.

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: cylinder, sparklet bulbs.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H280 Contains gas under pressure; may explode if heated.
Precautionary statements
  • P282 Wear cold insulating gloves and either face shield or eye protection.
  • P336+P317 Thaw frosted parts with lukewarm water. Do not rub affected area. Get medical help.
  • P403 Store in a well-ventilated place.
  • P410+P403 Protect from sunlight. Store in a well-ventilated place.

Substance as classified, dilutions may differ.

Questions

We have a box of old sparklet bulbs from a demonstration kit. What now?

Keep them boxed, cool and dry, and count them. Note any rust or damaged bulbs without trying to test or pierce them. They do not go in a general waste bin, and they do not go in a lab pack, so send a manual enquiry with the numbers.

Are used bulbs with a pierced seal ordinary scrap metal?

Do not assume so without checking. A pierced seal suggests a bulb has been used, but it is not proof that it is empty. Keep used bulbs separate from unused ones in a marked box and include both in your enquiry, so the right answer is given.

Should a part used incubator cylinder go back even if it still has gas in it?

Yes, cylinders are normally returned part full. Do not vent or empty it first. Close the valve, keep it upright and secured, and ask the supplier to collect it. If there is no supplier to be found, send a manual enquiry and include a photograph.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula CO2. EC number 204-696-9.

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