Chlorobutanol (CAS 57-15-8): storage and disposal
Chlorobutanol is a white solid kept as a preservative in university, histology and pharmacy stores, usually in a small jar from an old preparation or formulation. Its only classification given is harmful if swallowed, and the signal word is Warning. That mild profile means jars are often left at the back of a cupboard, so the work is mostly about finding, labelling and recording them.
- CAS number
- 57-15-8
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
A technician can check at the shelf that the jar has an intact cap and a label with a date, because small preservative jars lose both. It belongs in a dry, labelled, well organised general store, away from food items and clearly separated from pharmacy stock for use. Histology rooms keep it with fixatives and mounting reagents, and pharmacies among old formulation ingredients. Because it is harmful if swallowed, keep jars where they cannot be taken for a sweetener or other bench powder, and keep powder and crystals in the original container.
How to tell it has deteriorated
Few visible signs of ageing appear in a jar of chlorobutanol, so the container and record carry the evidence. Look for a lid that does not seat, a label that is stained, faded or missing a date, and clumps where damp has got into the powder. Crystals on the inside of the lid or at the neck are possible with an old and poorly sealed jar. Such changes are not a reason to open the jar. Record any caking or staining and list the jar for collection if the preparation it was bought for no longer exists.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
There is little to say about handling and plenty about description: a jar of chlorobutanol leaves by specialist collection, packed with compatible organic solids, and the list should state the form, the quantity and any label detail that remains. It must not be tipped into a sink, put in a medicines return bin or binned as an ordinary powder. A university or histology holder can use 16 05 06*, a loose discarded organic chemical can use 16 05 08*, and a pharmacy in a human healthcare setting can use 18 01 06*.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: preservative.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
Precautionary statements
- P264 Wash hands and exposed skin thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Is chlorobutanol a risky substance?
Its classification here is harmful if swallowed, with a Warning signal word. It is still a chemical waste that must be described accurately, and old jars should be labelled, kept out of reach and listed for collection.
The label on our jar has gone. What do we do?
Do not guess. Record where it was found and what the jar looks like, keep it sealed and ask for specialist advice. Tell the specialist collector that the solid is unidentified and provide the available information about its container, appearance and storage history so that classification can be arranged.
Can pharmacies return it through a medicines route?
Do not assume so. It is held here as a chemical ingredient and is classified as harmful if swallowed. Describe it on a collection request as chlorobutanol, state the form and quantity, and keep it in a labelled jar.
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