Chloroxylenol (CAS 88-04-0): storage and disposal
Antiseptic and disinfectant stock in school science stores, pharmacy shelves and clinic cupboards often includes chloroxylenol, a phenolic compound held as a solid or in solution. It is classified as harmful if swallowed, as causing skin and serious eye irritation, and as possibly causing an allergic skin reaction, which matters for the person who restocks the shelf.
- CAS number
- 88-04-0
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Because it can cause an allergic skin reaction, the habit that matters is not decanting it by hand. In a school or college store, keep the solid and any solutions in sealed, labelled containers on a general shelf with a date from arrival. The powder and the made-up solutions should not share a container, and ready-mixed antiseptic should be kept separate from the laboratory stock so that nobody uses a lab bottle for first aid. In a pharmacy or clinic, keep the bottle upright in a tray away from food. Phenolic products have a strong medicinal smell, so a tight cap is the first sign of good storage.
How to tell it has deteriorated
Powder or crystals should be loose and clean. Hard lumps, damp patches or clumps stuck to the glass mean the container has not been sealed. Solutions should be uniform. A deposit, a film, cloudiness that was not there before, or crust round the cap point to trouble. A strong smell in the cupboard before any bottle is opened suggests a cap that no longer seals. There is little else to see, so the visible checks are mostly on the container: faded or missing labels, softened plastic, staining on shelves and a bottle with no date.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
A school or college with an out-of-date bottle should say whether it is the solid or a solution, give the strength on the label and the volume left, and describe the container. The usual entry is 16 05 06*, a human healthcare setting usually uses 18 01 06*, and 16 05 08* covers a discarded organic chemical that is not part of a laboratory pack. Antiseptic is not rinsed away at a sink, put in the general bin or poured into a clinical waste container. Solutions and solid are listed separately and go in the collection as a registered carrier packs them in compatible groups.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: solid, solutions.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H315 Causes skin irritation.
- H317 May cause an allergic skin reaction.
- H319 Causes serious eye irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
What should happen to old chloroxylenol antiseptic?
Antiseptic that is out of date or no longer wanted is chemical waste and does not go down a sink. Keep it in its labelled container and arrange specialist collection. Do not dilute or treat it first.
How should staff avoid skin reactions when restocking?
The classification includes a possible allergic skin reaction, so avoid handling spilled liquid or powder with bare hands, and report any rash. Keep containers closed and check for residue on the outside. If a container is leaking or contaminated, report its condition rather than handling the residue during routine restocking.
What is different about the solid and the solutions?
The solid is held as powder or crystals and is checked for lumps and damp. Solutions are checked for deposit, cloudiness and cap residue. Describe them separately, with strength and volume, when you list them.
Which waste code does a pharmacy use?
School stock usually fits 16 05 06*, while a pharmacy or other human healthcare setting would usually use 18 01 06*. Give the setting and the description of the bottle when you enquire, and the waste producer confirms the entry.
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