Chrome alum (CAS 10141-00-1): storage and disposal
Chrome alum, the dark violet crystalline chromium potassium sulfate, is kept in school and college stores, university labs and histology rooms, where it is a long standing ingredient in slide adhesive. It is classified as irritating to skin, eyes and the respiratory tract, with a Warning signal word. Colour is the quickest guide to how a tub has been kept.
- CAS number
- 10141-00-1
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
A practical check at the shelf is colour: dark purple, glassy crystals in a tub that has not been moved for years suggest a sound seal, while pale, powdery or damp looking contents suggest air has got in. It sits comfortably in a dry, labelled, well organised store, dated on arrival, but because it irritates skin, eyes and the airways, wear gloves and eye protection and avoid raising dust. Keep it apart from food supplies and from the other alums, which look similar. Histology stores that use it for slide work should record who last opened it.
How to tell it has deteriorated
The dodecahydrate holds a lot of water, so the change to watch is the surface of the crystals: a dull, powdery bloom on the violet means water has been lost to dry air, and a wet, sticky or caked mass means water has been taken up from damp. Violet crystals that have turned greener are worth noting on the record. Old bottled solutions that have changed colour, clouded or grown mould have stood too long. Check also for a faded label, a crust at the neck, a cracked tub and no date of receipt. Each is recorded as found.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Pouring leftovers away is not an option: not into a sink, a drain, a general waste bin or a skip, and staff should not try to treat it first. Waste code 16 05 06* is the usual entry for a school or university holder, with 16 05 07* where it is a discarded inorganic chemical outside a lab pack and 18 01 06* in a human healthcare setting. Crystals and bottled solution are described and packed in separate groups. Record the container size, the amount left, the colour of the crystals and whether any solution has been made up from them.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: dodecahydrate.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H315 Causes skin irritation.
- H319 Causes serious eye irritation.
- H335 May cause respiratory irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P271 Use only outdoors or in a well-ventilated area.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why are chrome alum crystals purple?
The violet colour comes from hydrated chromium(III) ions in the crystal structure. Chrome alum normally forms dark violet crystals. A dull, powdery or pale surface, or a wet mass, can indicate changes in hydration and should be recorded.
What hazards does the classification list?
Skin irritation, serious eye irritation and respiratory irritation, with a Warning signal word. Wear gloves and eye protection, avoid raising dust and keep the lid closed between uses.
Can histology slide adhesive solution be kept?
A bottled solution that has clouded, changed colour or grown mould has stood too long. Record it separately from the dry crystals, keep the cap on and list it for collection.
Which waste code should a hospital histology lab use?
A human healthcare setting may use 18 01 06* in place of 16 05 06*. Say whether the stock sits in a hospital or university lab when you enquire about collection.
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