Chromium(III) chloride (CAS 10025-73-7): storage and disposal
Chromium(III) chloride hexahydrate is the dark green crystalline salt school, college and university stores use for transition metal chemistry. It is classified as harmful if swallowed, as possibly causing an allergic skin reaction and as toxic to aquatic life with long lasting effects. It can be kept on a suitably organised general chemicals shelf, with its identity and condition recorded accurately for specialist collection.
- CAS number
- 10025-73-7
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
Hazardous to the environment
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Check the neighbours before the lid. In a typical prep room this jar stands among other chromium compounds, and green chromium salts are easy to confuse with one another and with nickel or copper salts of a similar colour. Label it by full name and form, and keep it away from stock whose classification differs sharply. A dry general shelf is enough, since it needs no fire cabinet, but because it can cause an allergic skin reaction, handling with a clean spatula and not bare hands is sensible. The salt picks up moisture, so keep the cap tight and the jar on a tray, with the date received on the label.
How to tell it has deteriorated
Look for stickiness. Hydrated chromium chloride crystals can draw in water and clump, then leave a green wet film at the base of the jar and a damp ring on the shelf. A crust at the neck, a corroded cap and a label that has lifted with damp tell the same story. Colour is a poor guide because the salt is dark green whether fresh or old, though a jar that has gone paler or patchy on the surface has been exposed. This salt gives few dramatic signs with age, so the label, the date and the stock record carry most of the information.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
How it leaves the site is simple but must be accurate. It is a hazardous waste, so the stock is described as chromium(III) chloride hexahydrate, not as a general chromium salt, to avoid confusion with other chromium compounds. A laboratory pack uses 16 05 06* and discarded inorganic stock outside one uses 16 05 07*. Leftover solutions from practical work are bottled and described separately with an approximate volume. Neither the solid nor a solution may go into a sink or the ordinary bin because of the aquatic classification. Keep the original jar if it seals, and request a specialist collection.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: hexahydrate.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H317 May cause an allergic skin reaction.
- H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
- P260 Do not breathe dust, fume, gas, mist, vapours or spray.
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P284 In case of inadequate ventilation wear respiratory protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316 Get emergency medical help immediately.
- P320 Specific treatment is urgent (see supplemental first aid instruction on this label).
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P391 Collect spillage.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Is chromium(III) chloride classified the same as other chromium compounds?
Do not assume so. This entry is classified for harm if swallowed, skin allergy and aquatic effects. Label chromium compounds precisely and keep each to its own record, because they are classified very differently.
Why has the jar gone damp?
Hydrated crystals take water from the air, so a loose cap lets the salt clump and leave a wet green film. Keep it on a tray with the lid tight and record it for collection.
Can leftover green solution be tipped away?
No. It is toxic to aquatic life with long lasting effects. Collect it in a labelled bottle with a volume, and describe it separately from the solid in the request.
Does it need a special cabinet?
No. A dry general shelf is acceptable, with a tight lid and a tray. Take care over skin contact because it may cause an allergic skin reaction.
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