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Chemical collection and stock control for UK schools, universities and hospitals

Chromium(III) sulfate (CAS 10101-53-8): storage and disposal

Chromium(III) sulfate hydrate is a coloured crystalline or powdery stock in school, college and university stores, often green or violet depending on how it has been made and kept. It is not normally classified as hazardous, but it remains a chemical waste that has to be described accurately. The practical difficulty is that it is easily mistaken for neighbouring chromium salts.

CAS number
10101-53-8
Form
Solid
Storage class
General
Usual EWC code, laboratory stock
16 05 09

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Identification is the main job. Chromium stock on a prep-room shelf often includes sulfates, chlorides, oxides and compounds in other oxidation states, and several are classified differently from this one. Put it on a general shelf with its full name, the word hydrate and the date on the label, and keep it physically separate from other chromium jars so a technician reaching for one does not take the other. A tray and a tight lid guard against damp, and a dry cupboard suits it better than a damp bench. It needs no corrosive or fire store. Check the stock record against the label when the term starts.

How to tell it has deteriorated

This substance gives few visible signs of age. The colour can differ between jars without meaning much, so do not use it as a marker, though a jar that has turned patchy or developed a hard crust has probably taken in moisture. Look at the container: clumping, caked powder round the neck, a cap that has stuck and a label that no longer names the exact compound. A jar of green or violet powder with a worn label and no date should be treated as an unidentified chromium salt until its identity is confirmed, since neighbouring chromium compounds are classified differently.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

It leaves the site as a chemical waste under a waste transfer note, even though it is not normally classified as hazardous. The usual code is 16 05 09, though the producer classifies the waste. Describe it precisely as chromium(III) sulfate hydrate and note the colour and condition, because a vague entry such as chromium salt could be read as something else entirely. Leftover solution from a practical goes into a labelled bottle, not a sink or drain. Keep the original jar if the seal is sound. Nobody should try to precipitate or treat the stock first. Request a specialist collection and say how many jars there are.

Waste codes for Chromium(III) sulfate
Usual EWC code, laboratory stock16 05 09
Usually classed as hazardous wasteNo

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: hydrate.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Questions

Is chromium(III) sulfate hazardous waste?

It is not normally classified as hazardous, but it is still a chemical waste. It needs an accurate description and a waste transfer note and goes by specialist collection.

Why does the colour differ between our jars?

Hydrated chromium sulfate can look green or violet, so colour alone is not a reliable marker. Rely on the label, the date and the stock record, and describe each jar as you find it.

How do we avoid mixing it up with other chromium salts?

Label by full name and form, keep chromium jars on separate shelf positions, and check the stock record against the labels. Neighbouring chromium compounds are classified differently.

What should happen to leftover solution?

It must never go down a drain, because it remains chemical waste. Keep it in a labelled bottle, give an approximate volume and include it in your collection request.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Cr2O12S3. EC number 233-253-2.

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