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Chemical collection and stock control for UK schools, universities and hospitals

Copper(II) carbonate (CAS 12069-69-1): storage and disposal

Basic copper(II) carbonate is the green powder in school, college and university stores that is heated in thermal decomposition practicals. It is classified as harmful if swallowed or inhaled, as causing serious eye irritation and as very toxic to aquatic life with long lasting effects. A lesson set often leaves several part-used tubs of it, some with black residue from earlier classes mixed in.

CAS number
12069-69-1
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant
  • Hazardous to the environment pictogramHazardous to the environment

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Check what the green tub is sitting beside. Basic copper carbonate belongs on a general shelf in a dry, labelled store, dated on arrival, away from food grade supplies and clear of the acid store, because acids attack carbonates. The classification includes harm if inhaled, so a fine powder that rises on opening needs a lid that seats properly and a clean outside. Tubs issued for decomposition practicals should return to the store with the label intact, and any that have been used to hold heated residue should be labelled as such, not shelved as clean stock.

How to tell it has deteriorated

Clean stock is a bright green powder that runs freely. The main finding in school stores is a tub that is no longer clean: green powder streaked with black, which is what remains after heating, shows that used material has gone back into stock. Clumping points to damp, and green dust around the lid points to a loose seal. A faded label and an unknown date of receipt are common. A tub that is mixed green and black is neither fresh carbonate nor pure oxide and should be described as a mixture of unknown proportion, not returned to use.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Mixed stock is what makes this item awkward. A tub of green powder with black residue is partly copper(II) carbonate and partly something else, and it should be listed as mixed with an honest note of what you know about it. Keep clean stock and used residue in separate containers, each closed. Because it is classified as very toxic to aquatic life, heated residue included, it must not go down a sink or drain, into general waste or into a skip, and nobody should try to treat it first. It is hazardous waste, normally collected under 16 05 06* in a lab pack or 16 05 07* outside one, though the producer classifies the waste.

Waste codes for Copper(II) carbonate
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: basic carbonate.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H319 Causes serious eye irritation.
  • H332 Harmful if inhaled.
  • H410 Very toxic to aquatic life with long lasting effects.

Substance as classified, dilutions may differ.

Questions

Can heated residue from the practical go back in the tub?

No. Heated residue is no longer copper carbonate, and mixing it back leaves stock you cannot describe. Keep residue in its own labelled container and have it collected.

Why keep it away from acids?

Acids attack carbonates, so a spill or a leaking acid bottle above a carbonate tub turns a minor leak into a bigger one. Keep it out of the corrosive store and off shelves beneath acid stock.

Does the green powder go off?

It is a stable solid with few visible signs of ageing. The usual problems are damp clumping, a loose lid and mixed black residue. Check the container, label and record, and put forward any tub that is undated or contaminated.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: GB mandatory classification list (HSE), retrieved 31 Oct 2026. Formula CH2Cu2O5.

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