Copper(II) chloride (CAS 7447-39-4): storage and disposal
Copper(II) chloride dihydrate is a blue-green crystalline salt held in school, college and university stores, used in displacement and flame test work. It is classified as harmful if swallowed or in contact with skin, a skin irritant, a cause of serious eye damage and very toxic to aquatic life with long lasting effects. A damp, green-stained jar is the typical finding on an old shelf.
- CAS number
- 7447-39-4
- Form
- Solid
- Storage class
- General
- Signal word
- Danger
- Usual EWC code, laboratory stock
- 16 05 06*
Corrosive
Harmful or irritant
Hazardous to the environment
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
On a school shelf it often sits between copper sulfate and copper nitrate in a row of blue-green jars, and the labels matter more than the colours because the three have different classifications. It is general class stock, so a dry, labelled, well organised store suits it, dated on arrival and kept away from food grade supplies. Close the cap firmly each time: the salt takes up moisture, and a loose lid lets it become wet and then attack the cap. Because of the serious eye damage classification, handle any jar with a cracked neck as an eye risk.
How to tell it has deteriorated
The dihydrate should be blue-green crystals that run freely. In a humid store they take up moisture, clump and may become a damp green mass, and the liquid then reacts with metal, so a green crust on the cap and a corroded or seized lid are typical. Green staining on the shelf under the jar shows that liquid has escaped. A label attacked by seepage, a cracked jar and an unknown date of receipt are further signs. A wet jar is still copper chloride, so describe it as it is and do not move the contents into another container.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
It is classified as very toxic to aquatic life, so it must not go down a sink or drain, into general waste or into a skip, and nobody should try to treat it first. Collection is by the specialist route as hazardous waste, normally using 16 05 06* in a lab pack or 16 05 07* outside one, though the producer classifies the waste. Damp stock is the awkward item: a jar with green liquid or a corroded cap needs describing as such and should travel upright, ideally inside a second container. Record the form, which is normally the dihydrate, and the approximate amount, and tell the collection team about any seepage.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: dihydrate.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H312 Harmful in contact with skin.
- H315 Causes skin irritation.
- H318 Causes serious eye damage.
- H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
- P234 Keep only in original packaging.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P390 Absorb spillage to prevent material damage.
- P391 Collect spillage.
- P406 Store in corrosive resistant container with a resistant inner liner.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why is there green crust on our copper chloride jar?
The salt takes up moisture, and the damp solution attacks metal caps and creeps over the thread. It means the lid has not been tight or the store is humid. Keep the jar upright and describe the seepage for collection.
How is it different from copper sulfate on the shelf?
It is classified for serious eye damage and as harmful in contact with skin, as well as aquatic toxicity, and it takes up water. Label the jars clearly because the blue-green colours are easy to confuse.
Can a wet jar be collected?
Yes. Say it is wet, keep the cap tight and the jar upright, and do not decant the liquid. The collection team will pack it with the condition in mind.
Related chemicals
Search the chemical database- 1,1,1-TrichloroethaneCAS 71-55-6General
- 1-NaphtholCAS 90-15-3General
- 2-NaphtholCAS 135-19-3General
- 3,3',5,5'-TetramethylbenzidineCAS 54827-17-7General
- 4-NitrophenolCAS 100-02-7General
- AcetophenoneCAS 98-86-2General