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Chemical collection and stock control for UK schools, universities and hospitals

Dichlorophenolindophenol (CAS 620-45-1): storage and disposal

Anyone who has run a vitamin C practical will know dichlorophenolindophenol, usually as the dark sodium salt or as a blue DCPIP solution in a small bottle. It is classified as causing skin and serious eye irritation and may cause respiratory irritation. School, college and university stores often hold both forms, and the solution is the one that changes visibly on the shelf.

CAS number
620-45-1
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

The container or form it arrives in matters here, since the sodium salt and the solution are kept differently. The dry salt goes in a dry, labelled store, with the lid tightly closed, away from food grade supplies. A bottle of DCPIP solution should be kept out of bright light, such as a windowsill or open shelf under a lamp, and in a tray. Because the salt may cause respiratory irritation, avoid opening the jar in an unventilated cupboard. Date every bottle of solution on arrival or when it was filled, since an undated bottle cannot be judged at all.

How to tell it has deteriorated

In its working state the solution is a strong blue, and the powder is a dark, rich colour. What does not look right is a solution that has gone pale, murky or colourless on its own, which suggests it has faded with age or light and no longer behaves as an indicator. A dried crust at the neck, a split label, and a powder that has caked from damp are the container signs. A bottle with no date or maker is the commonest problem. Record the colour you see, the level and the cap condition, and do not open a cloudy bottle.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Waste code 16 05 06* applies to a laboratory chemical in a lab pack, and 16 05 08* where it counts as discarded organic chemical outside one. The salt and the solution are listed as separate items, since the solution is a liquid and the salt is a solid. Both go by specialist collection, and neither should be poured down a sink, because nobody should assume a coloured indicator solution is safe to flush. Record the label wording, the container type and the approximate volume, and keep the cap tight until collection.

Waste codes and transport details for Dichlorophenolindophenol
EWC code, laboratory chemicals16 05 06*
Discarded organic chemical, not a laboratory pack16 05 08*
Hazardous wasteYes

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: sodium salt, DCPIP solution.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Hazard statements

  • H315 Causes skin irritation.
  • H319 Causes serious eye irritation.
  • H335 May cause respiratory irritation.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Our DCPIP solution has lost its blue colour. Is it waste?

A solution that has faded or turned colourless on the shelf no longer works as an indicator, so it is surplus. It is still a chemical waste and should be described accurately. Keep the cap tight, record the colour and date, and request collection.

Is DCPIP powder an irritant?

It is classified as causing skin and serious eye irritation and may cause respiratory irritation. Keep the jar closed, avoid creating dust and wear the gloves and eye protection your own risk assessment sets out. These are the classified effects, not a full assessment of your use.

Do the salt and solution travel together?

They are listed as two items because one is a solid and the other a liquid. The collector groups them into compatible lab packs. Give each its own label wording and quantity when you request collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C12H6Cl2NNaO2. EC number 210-640-4.

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