Dipotassium hydrogen phosphate (CAS 7758-11-4): storage and disposal
A white buffer salt held in school, college and university stores and in pathology labs, dipotassium hydrogen phosphate is classified as causing skin irritation, with a Warning signal word. Its main habit on the shelf is drawing water from the air. A tub that has been opened a few times will often be clumped, which is a condition record more than a hazard sign.
- CAS number
- 7758-11-4
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Bought as a tub of buffer stock, it should go on a dry shelf with the lid screwed tight after each use, as damp air gets into this salt quickly. Because it irritates skin, gloves are sensible when scooping, and spilt crystals should be reported and not wiped into other stock. The dibasic and monobasic phosphates look the same, so write the full name on the label and date the tub on arrival. A dry, labelled, well organised store is the baseline, with food grade supplies kept separate from laboratory stock. Pathology and university labs often hold several phosphate salts together.
How to tell it has deteriorated
This salt draws water readily, so an old tub is often one solid cake or a damp, sticky mass instead of loose crystals. A crust around the neck and a wet ring on the shelf below show the lid has not been sealing. Buffer solutions made from phosphate go cloudy or grow mould once they have stood too long. Check also for a faded label, a cracked tub and an unknown date of receipt. Everything is described as found. A caked tub is not a reason to open it or break the lump.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
The asterisk on 16 05 06* marks hazardous waste, which is the usual code for this item. A pathology store in human healthcare would use 18 01 06*, and a discarded inorganic chemical outside a lab pack takes 16 05 07*. Dry stock and any bottled solution travel in separate groups, and a leaking cap is described so the packers know. No sink, drain, general waste bin or skip is the route, and staff should not try to treat it first. Record the tub size, the amount left and whether it has caked or run damp.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: buffer stock.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H315 Causes skin irritation.
Precautionary statements
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
Substance as classified, dilutions may differ.
Questions
Why has the tub set into a solid lump?
The salt takes water from the air and cakes. Keep the lid tight, store it dry and record the tub as caked. Do not break up the lump, and list it for collection when it is no longer needed.
What hazard does the classification list?
Skin irritation, with a Warning signal word. Use gloves when handling it, wash any contact promptly, and keep spilt crystals away from other stock until they have been reported.
Is it the same as potassium dihydrogen phosphate?
No. They are the dibasic and monobasic salts, with different classifications and codes, so label each in full and shelve them apart, particularly in a pathology or university store.
Does the dibasic salt need a locked cabinet?
No special lock is needed. A dry, labelled, well organised shelf with a dated record is the baseline, with food grade supplies kept separate from laboratory stock.
Related chemicals
Search the chemical database- 1,1,1-TrichloroethaneCAS 71-55-6General
- 1-NaphtholCAS 90-15-3General
- 2-NaphtholCAS 135-19-3General
- 3,3',5,5'-TetramethylbenzidineCAS 54827-17-7General
- 4-NitrophenolCAS 100-02-7General
- AcetophenoneCAS 98-86-2General