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Chemical collection and stock control for UK schools, universities and hospitals

Helium (CAS 7440-59-7): storage and disposal

Helium reaches schools and colleges in small cylinders, often bought for balloons or physics work, while universities also use larger cylinders and liquid helium for instruments. It is a gas under pressure that may explode if heated, refrigerated forms can cause cryogenic burns or injury, and a leak in a closed room can displace oxygen. Nobody should breathe it from a cylinder or balloon, because it can cause asphyxiation. The gas itself does not change with age, so a cylinder's owner, and whether it is a returnable or a single use type, decide what happens next.

CAS number
7440-59-7
Form
Gas
Storage class
General
Signal word
Warning
Usual EWC code
16 05 05
  • Gas under pressure pictogramGas under pressure

This chemical is a manual enquiry

This is a gas held under pressure, liquefied or in solid or cryogenic form. Cylinders and dewars are usually returned to the supplier or handled separately, and they do not go into a laboratory pack.

Held as a compressed or liquefied gas in a pressure container.

It cannot be priced through a form. Please do not open or move it. Call us or send an enquiry and we will talk through the next step, which depends on what it is. Keep following your own procedures for controlled drugs, radioactive materials, gases and asbestos.

What to do this week

  1. Leave it where it is. If it looks old, crystalline or damaged, do not open or move it and keep people away from the shelf. If there is immediate danger, such as a leak, fumes or a fire, leave the area and call 999.
  2. Write down the label wording, the rough age and where it is stored, from a safe distance.
  3. Send us those details, and a photo if you can take one without touching it.

Safe storage in a school or lab

Check whether the cylinder is hired or bought outright. A label naming a gas company usually means it goes back to them, whereas a small balloon kit canister bought for an open day may have no owner to return to at all. That check saves trouble later. Either way, keep it upright and secured, in a stand or strapped to something fixed, well clear of radiators, stage lighting and direct sun. Schools often leave a cylinder in a drama cupboard or a corner of the hall after an event, unchained and forgotten, so add it to the record with its location and secure it where it stands. University holders of liquid helium should treat those vessels separately. Do not puncture or vent a cylinder to finish it off.

How to tell it has deteriorated

Dents and scuffs on a small canister are what a technician will see first, because these often get carried around for events and thrown in cupboards. Helium itself shows nothing with age, so there is no chemical sign to find and the gas stays as it was. The steel and valve are where the changes appear. Look for rust at the base, a bent valve, a missing guard or a label too worn to read. Balloon kit nozzles left on a canister can be knocked and start a slow leak, and helium escapes readily, so a cylinder may be emptier than its last use suggests. Even so, treat one that seems empty as a pressure container, since looks prove nothing about its contents.

How it is disposed of

This does not go through our standard collection route. It is arranged by manual enquiry, and never goes down the drain or into general waste.

Pressure containers cannot be grouped into a lab pack, whichever gas they hold, so helium is dealt with item by item and not through packing. A hired cylinder goes back to its supplier. Single use canisters and any cylinder with no traceable owner call for a manual enquiry, because this site does not quote for them online. Give the number, size, any label wording and where each stands, and a photograph helps. A store assessment is recommended if a department has built up several. Keep each one upright and secured while you wait for advice. Do not vent, puncture or crush a canister, even when it seems to be empty, and do not put one in a general waste bin or a skip.

Waste codes for Helium
Usual EWC code16 05 05
Usually classed as hazardous wasteNo

Gases in pressure containers are assessed by manual enquiry, usually with return to the cylinder owner.

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: cylinder.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H280 Contains gas under pressure; may explode if heated.
Precautionary statements
  • P282 Wear cold insulating gloves and either face shield or eye protection.
  • P336+P317 Thaw frosted parts with lukewarm water. Do not rub affected area. Get medical help.
  • P403 Store in a well-ventilated place.
  • P410+P403 Protect from sunlight. Store in a well-ventilated place.

Substance as classified, dilutions may differ.

Questions

We have a balloon kit canister left from a school event. Can it go in the recycling?

Do not put it in recycling or a general waste bin on the strength of its feeling light, as it may still hold gas under pressure. Keep it upright and away from heat, read the label for any supplier and send a manual enquiry if there is none.

How do we tell a hired cylinder from one we own?

Look for a supplier name, a rental or barcode tag and any ownership wording on the label or the shoulder. Check your purchase records as well. Most cylinders of this type belong to the gas company and go back to them, whatever the age.

Our cylinder has been in a cupboard for years. Is the gas still usable?

The gas does not break down with age, but the cylinder may be another matter. Rust, a bent valve or a worn label are reasons to stop using it and to raise it with the supplier. Keep it upright and secured in the meantime.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula He. EC number 231-168-5.

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