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Chemical collection and stock control for UK schools, universities and hospitals

Hydroxyethyl methacrylate (CAS 868-77-9): storage and disposal

Dental bonding agents and resin research in university labs both rely on hydroxyethyl methacrylate, a reactive monomer held neat or as a component of an adhesive. It is classified as causing skin irritation and serious eye irritation, and as possibly causing an allergic skin reaction. The sensitiser classification is the one dental teams should keep in mind when handling spills.

CAS number
868-77-9
Form
Liquid
Storage class
General
Signal word
Warning
Usual EWC code
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

One small bottle on a surgery shelf is easy to forget, so check the cap and the neck at the same time as the date. Methacrylate monomers are reactive liquids, and heat and light are the usual enemies, so keep the bottle in a cool cupboard away from the curing lamp, the sterilising unit and windows. In a dental store it should be kept apart from the cements and etchants so that a cap is not swapped. Because it may cause an allergic skin reaction, nobody should handle a leaking bottle bare-handed, and repeated small spills on a shelf are worth cleaning with care. Label it with the name and the date of receipt and keep it upright in a tray.

How to tell it has deteriorated

A clear, thin, colourless liquid is what a sound bottle holds. A monomer that is going off tends to thicken, turn syrupy, become cloudy or leave a rubbery film or gelled lumps in the neck and on the dropper. Those changes mean the liquid has started to set in the bottle. A warm bottle, one that feels soft or looks swollen, or a liquid that has set solid should not be opened. Beyond that, check for sticky residue on the cap, a perished dropper, faded labels and a missing date. Any bottle that has thickened or set should be listed for collection rather than being used up.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Write the waste code and the form on the list together: 16 05 06* for a university lab, 18 01 06* in a human healthcare setting such as a dental surgery, and 16 05 08* where it is a discarded organic chemical outside a laboratory pack. Say whether it is neat monomer or part of an adhesive kit, and whether the liquid has thickened. Because it is a sensitiser, bottles with sticky threads are described as such. Leftover liquid does not go in a sink, in a clinical waste sharps bin or in the general bin, and nobody should try to cure or set it first. A registered carrier collects it.

Waste codes and transport details for Hydroxyethyl methacrylate
EWC code, laboratory chemicals16 05 06*
Discarded organic chemical, not a laboratory pack16 05 08*
Human healthcare setting18 01 06*
Hazardous wasteYes

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: neat, dental adhesive component.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Hazard statements

  • H315 Causes skin irritation.
  • H317 May cause an allergic skin reaction.
  • H319 Causes serious eye irritation.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P332+P317 If skin irritation occurs: Get medical help.
  • P333+P317 If skin irritation or rash occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Our HEMA bottle has thickened. Can we still use it?

Thickening, cloudiness or lumps mean the monomer has begun to set in the bottle, so it is no longer reliable stock. Do not warm it or try to loosen it. Record it and list it for collection.

Can leftover bonding adhesive be allowed to set and then thrown away?

No. Setting leftover resin deliberately is a form of treatment and is not acceptable. Keep it in its labelled container, with the kit if it came in one, and arrange specialist collection.

Where should it be kept in a dental store?

In a cool cupboard away from the curing lamp, sterilising equipment and windows, upright in a tray, and away from etchants and cements. Label it and keep the date visible.

Why is skin contact such a concern?

It is classified as possibly causing an allergic skin reaction, so repeated contact can matter more than a single splash. Avoid handling leaking bottles bare-handed and report any rash from the work.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C6H10O3. EC number 212-782-2.

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