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Chemical collection and stock control for UK schools, universities and hospitals

Iodoethane (CAS 75-03-6): storage and disposal

Iodoethane sits in college and university stores as a neat liquid in small glass bottles. Its classification covers harm if swallowed, skin and eye irritation, an allergic skin reaction, respiratory irritation and, unusually for a bottle on the general shelf, allergy or asthma symptoms if inhaled. Its general storage class says little about the real concern, which is who is allowed to open it and whether the light has got to it.

CAS number
75-03-6
Form
Liquid
Storage class
General
Signal word
Danger
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant
  • Serious health hazard pictogramSerious health hazard

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

A dry, labelled, well organised store suits it, with the stock in a dark glass bottle or closed box, away from direct light. The sensitising effects matter more than the class suggests: someone who has become sensitised by inhalation may react to very small exposures, so keep the list of people who handle it short, and work with it only in a fume cupboard. In a university lab the bottle often sits among other alkyl halides in matching glass, so check that the name on the label is the right one. Keep it away from food supplies.

How to tell it has deteriorated

Light is the thing iodoethane suffers from. A clear liquid slowly turns yellow, then brown as iodine is released, and an old bottle may leave brown staining on the cap, neck and shelf. Stained labels, a dried cap liner and a lowered level also show age. Because a vapour leak could affect a sensitised person, a bottle whose cap has failed or whose smell reaches the room should be reported and left alone. Do not open a browned bottle to look inside, and note the colour on the record.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Specialist collection is the only route for iodoethane, in compatible groups of halogenated organics. It must not be poured away, evaporated or moved to a fresh bottle, and nobody should try to treat discoloured stock. Say on the list that it is browned if it is, give the size and level, and mention any staining on the cap. The usual list code is 16 05 06* for packed laboratory stock, and a loose discarded organic chemical not sent in a pack can use 16 05 08*. Keep the label legible until collection.

Waste codes for Iodoethane
Usual EWC code, laboratory stock16 05 06*
Discarded organic chemical, not a laboratory pack16 05 08*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: neat.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H315 Causes skin irritation.
  • H317 May cause an allergic skin reaction.
  • H319 Causes serious eye irritation.
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335 May cause respiratory irritation.
Precautionary statements
  • P203 Obtain, read and follow all safety instructions before use.
  • P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P233 Keep container tightly closed.
  • P240 Ground and bond container and receiving equipment.
  • P241 Use explosion-proof electrical, ventilating and lighting equipment.
  • P242 Use non-sparking tools.
  • P243 Take action to prevent static discharges.
  • P260 Do not breathe dust, fume, gas, mist, vapours or spray.
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P284 In case of inadequate ventilation wear respiratory protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P317 Get medical help.
  • P318 If exposed or concerned, get medical advice.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P333+P317 If skin irritation or rash occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P342+P316 If experiencing respiratory symptoms: Get emergency medical help immediately.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P370+P378 In case of fire: Use suitable extinguishing media to extinguish.
  • P403 Store in a well-ventilated place.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P403+P235 Store in a well-ventilated place. Keep cool.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Why has our iodoethane gone yellow-brown?

Light releases iodine from it over time, so the liquid yellows and then browns and can stain the cap and shelf. It is still iodoethane for disposal. Keep it capped, dark and labelled, and list it for collection.

Why does it matter that it can cause allergy or asthma symptoms?

Inhalation can trigger allergy or asthma symptoms, and once someone is sensitised even small exposures can matter. Limit who handles it, use a fume cupboard, and report any staff reaction through your health and safety route.

Is a general storage class enough for iodoethane?

The class gives a dry, labelled, organised store, but the hazards also call for a dark bottle, a short list of handlers and handling in a fume cupboard. Your risk assessment should decide the final arrangement.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C2H5I. EC number 200-833-1.

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