Iodoform (CAS 75-47-8): storage and disposal
Iodoform is a yellow crystalline solid with a medicinal smell, held in school and university stores, in pharmacies as legacy dressing and in dental surgeries as paste. It is harmful if swallowed, in contact with skin and if inhaled, irritates skin, eyes and airways. Pharmacy and dental stock is usually old, small and half-forgotten, so condition and labelling decide most of what happens to it.
- CAS number
- 75-47-8
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
A quick shelf check is whether the jar is in a dark glass container with a tight lid, because light and air are what damage iodoform and the smell escapes through poor seals. It sits in a dry, labelled, well organised store, away from food items. Dental surgeries tend to keep it as a paste or in tubes in the cupboard with root canal materials, and pharmacies as old impregnated dressings in tins, so each kind of stock should stay in its own container with the label facing out. Date any item that lacks a date of receipt.
How to tell it has deteriorated
Light is the main enemy of iodoform, and old stock usually shows it. The bright yellow crystals darken towards brown, a sharp iodine-like smell builds up in the cupboard, and the cap or lid may stain brown. Tins of old dressing can corrode and leave rust or brown marks on the shelf, and dental paste tubes may split or dry to a crust. Faded labels and missing dates are common with pharmacy stock. A jar that has stained its surroundings brown should be left in place on a tray and recorded rather than opened to look inside.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
Whether it is a jar of crystals, a tin of dressing or a dental paste tube, iodoform goes the same way: by specialist collection, packed with compatible organic solids. Do not put old dressing in ordinary clinical waste without a waste assessment, and do not wash paste or crystals down a sink. Say on the list which form each item takes and what its label states. School and university stock fits 16 05 06*, a loose discarded organic chemical not sent in a pack can use 16 05 08*, and a pharmacy or dental practice can use 18 01 06*.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: legacy dressing, dental paste.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H312 Harmful in contact with skin.
- H315 Causes skin irritation.
- H319 Causes serious eye irritation.
- H332 Harmful if inhaled.
- H335 May cause respiratory irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why has our iodoform gone brown?
Light and air slowly release iodine from it, so yellow crystals darken and a sharp smell develops. It is still iodoform for disposal. Keep the jar closed and labelled in a dark store, and list its colour when arranging collection.
Can old iodoform dressings go in clinical waste?
No. The substance is classified as harmful by swallowing, skin contact and inhalation, so old impregnated dressing should not go in ordinary clinical waste without a waste assessment. Keep it in its tin or wrapper and arrange specialist collection.
How should a dental surgery store iodoform paste?
Keep tubes upright in a closed cupboard with the root canal materials, in the original packaging with the label visible. Check for split tubes and dried crusts at each stock review, and list any expired items for collection.
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