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Chemical collection and stock control for UK schools, universities and hospitals

Iron(III) sulfate (CAS 10028-22-5): storage and disposal

Iron(III) sulfate is held as a hydrate in school, college and university stores, and as haemostatic solutions in dental surgeries. It is classified as possibly corrosive to metals, harmful if swallowed, a skin irritant and a cause of serious eye damage. Dental holders usually have small bottles of solution with expiry dates, while teaching labs have a jar of solid, and the two are described differently.

CAS number
10028-22-5
Form
Solid
Storage class
General
Signal word
Danger
Usual EWC code, laboratory stock
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Because it may be corrosive to metals, keep it off bare metal shelving and out of metal tins, on a tray in a dry, labelled store. In a dental surgery the haemostatic solution sits in a cupboard with other materials, and the bottle should be kept upright with the cap tight and the expiry date visible. The solid hydrate in a teaching store is general class stock, dated on arrival and kept away from food grade supplies. Because of the serious eye damage classification, handle a cracked bottle or a jar with a crusted neck as an eye risk.

How to tell it has deteriorated

Check the container's metal parts first. A solution or a damp solid that may be corrosive to metals shows up as rust or pitting on a cap, a nearby shelf or a tray, and as a brown or yellow stain where liquid has crept out. Solid stock can clump if damp. For dental solutions, look at the expiry date, the cap, the label and the level in the bottle, and for a change in colour or any sediment. A bottle that is past its date or has no readable label should be set aside and recorded. Altered stock is still iron(III) sulfate.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Dental surgeries are the main complication. A small bottle of haemostatic solution is a ready-made product with an expiry date, and it should be described as such, with the original label visible and the cap tight. Solid hydrate from teaching stores is described by form and amount. A dilute solution may be less hazardous than the solid, but it is still chemical waste. It is normally hazardous waste, usually collected under 16 05 06* in a lab pack or 18 01 06* in a human healthcare setting, though the producer classifies the waste. It must not go into a sink, a drain, general waste or a skip, and nobody should try to treat it first.

Waste codes for Iron(III) sulfate
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: hydrate, haemostatic solutions.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H290 May be corrosive to metals.
  • H302 Harmful if swallowed.
  • H315 Causes skin irritation.
  • H318 Causes serious eye damage.
Precautionary statements
  • P234 Keep only in original packaging.
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P317 Get medical help.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P333+P317 If skin irritation or rash occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P390 Absorb spillage to prevent material damage.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P405 Store locked up.
  • P406 Store in corrosive resistant container with a resistant inner liner.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Can dental haemostatic solution be collected?

Yes. Describe it as a ready-made solution, keep it in its labelled bottle with the cap tight and note the expiry date. The practice manager should list it separately from any laboratory solid.

Why does it matter that it may be corrosive to metals?

Liquid that escapes can attack metal caps, trays and shelving, which in turn can weaken a container. Store it on a tray, off bare metal, and check caps and shelves for rust and staining.

What do we do with an expired bottle?

Keep it upright with the cap tight and the label legible, record the expiry date, and put it forward for collection. Do not top it up or combine it with other bottles.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Fe2O12S3. EC number 233-072-9.

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