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Chemical collection and stock control for UK schools, universities and hospitals

Lithium chloride (CAS 7447-41-8): storage and disposal

Lithium chloride is a white solid kept in school, college and university stores, often as part of a flame test set. It is classified as harmful if swallowed, as causing skin irritation and as causing serious eye irritation, and is treated as hazardous waste. It is a salt that takes up water from the air very readily, so the state of a jar after a few humid months is the main thing to describe.

CAS number
7447-41-8
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Flame test sets are where it most often sits, and the set is carried from store to bench and back again. Each time the jar is opened in a damp room it takes in water. Keep the lid screwed on firmly and the jar in a dry, labelled, general store, dated on arrival, away from food grade supplies. Because the classification includes skin and eye irritation, spilled crystals and the film left by a wet jar need care when wiped up. Where a school keeps several chlorides together, make sure the lithium chloride jar has its own clear label so it is not mistaken for sodium chloride.

How to tell it has deteriorated

Dry, free-flowing white crystals are the starting point. Lithium chloride draws water readily, so an older jar tends to show clumps, then a solid cake, and in a poor seal a wet paste or liquid at the base. Look at the cap for crust or corrosion, at the shelf for a damp ring and at the label for staining. A jar that has become one fused block cannot be sampled without breaking it, which is a reason to leave it alone. Whatever state it is in, it remains lithium chloride and keeps its classification, and it should not be tipped into a fresh jar.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Most of the difficulty is liquid. A jar that has taken in water can leak in transit, so keep the cap tight, stand it upright and say on the request whether the contents are dry, caked or wet. Do not decant it or try to dry it out. Hazardous waste entry 16 05 06* normally applies in a lab pack and 16 05 07* outside one, though the producer classifies the waste. Because it looks like many white salts, check the label against what is inside as far as can be done without opening the jar. It must not go into a sink, a drain, general waste or a skip, and nobody should try to treat it first.

Waste codes for Lithium chloride
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: solid.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H315 Causes skin irritation.
  • H319 Causes serious eye irritation.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Why has our lithium chloride turned into a paste?

It takes water from the air readily, so a loose lid or repeated opening in a damp room lets it clump, cake and then go wet. The contents are still lithium chloride. Keep the jar upright and closed and describe its condition.

Can we scrape a caked jar loose for the next lesson?

Better not. Breaking up caked salt spreads dust and splashes, and the stock is classified as causing skin and eye irritation. Put a fused jar forward for collection and use fresh stock.

Is lithium chloride hazardous waste?

Yes. It is classified as harmful if swallowed and as causing skin and serious eye irritation, so it is treated as hazardous waste. A dilute solution may be less hazardous, but it is still collected as chemical waste.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula ClLi. EC number 231-212-3.

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