Magnesium hydroxide (CAS 1309-42-8): storage and disposal
School, college and university stores hold magnesium hydroxide as a fine white powder, used in antacid and acid reaction demonstrations. It is not classified as hazardous on the sources we checked, but it remains a chemical waste that needs an accurate description. Most problems come from the slurries and suspensions made from it, which settle, grow a film or lose their labels, rather than from the powder itself.
- CAS number
- 1309-42-8
- Form
- Solid
- Storage class
- General
- Usual EWC code
- 16 05 09
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
In a school prep room magnesium hydroxide usually shares a shelf with other white powders such as magnesium oxide and calcium carbonate, so the label does the work and not the look of the powder. Keep it in a dry, closed, labelled tub, dated on arrival and apart from food grade supplies. Any suspension made from it should be in a capped bottle labelled with the name and date made, since a settled white slurry looks like milk of magnesia. University stores should list powder and suspension separately and keep the tub away from damp.
How to tell it has deteriorated
Good magnesium hydroxide is a fine white powder, soft and free of lumps. Caking or a damp, clumped feel means moisture has entered. The powder gives few other visible signs. Suspensions are different: the solid settles to a layer at the base, and that is normal, but a film, floating specks, a smell or a change from white to something else suggests growth in the bottle. A crust at the cap, a cracked tub or an unreadable label counts as a problem. Anything unlabelled should be left closed and recorded.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Do not wash it down the sink because it is a white powder that looks inert: magnesium hydroxide must not go into a sink, a drain, a general waste bin or a skip, and nobody should try to treat it first. Not being classified as hazardous on the sources we checked does not change that. It leaves by specialist collection with compatible solids, and a waste transfer note covers it under entry 16 05 09. Say whether the stock is powder or suspension, give the container size, and mention anything added to a suspension.
| EWC code, laboratory chemicals | 16 05 09 |
|---|---|
| Hazardous waste | No |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: solid.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Questions
Can magnesium hydroxide go in the bin since it is an antacid ingredient?
No. The antacid use does not change its status in a laboratory. It is a chemical waste, not classified as hazardous on the sources we checked, and it must be described accurately and collected by specialist route, not placed in general waste.
Why has our magnesium hydroxide suspension separated?
The solid settles to the bottom over time, which is expected. A film, floating specks or a changed look suggests growth in the bottle. Keep it closed and labelled, and treat an undated or doubtful bottle as waste.
How do we tell magnesium hydroxide from magnesium oxide on the shelf?
The label is the only reliable guide, as both are fine white powders. Check that the name is complete, date new tubs on arrival and never decant into unmarked containers. Record unlabelled white powders as unknown for collection.
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