Magnesium oxide (CAS 1309-48-4): storage and disposal
Fine white magnesium oxide powder sits on school, college and university shelves for combustion work and as a reagent. It is not normally classified as hazardous, but it is still a chemical waste that needs accurate description. Stock tends to accumulate for years because it is rarely used up, and jars outlast their labels.
- CAS number
- 1309-48-4
- Form
- Solid
- Storage class
- General
- Usual EWC code, laboratory stock
- 16 05 09
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Keep magnesium oxide away from anything that will wet it. Light grades take up water and carbon dioxide from the air, slowly becoming a lumpy mix with magnesium hydroxide and carbonate, so a tightly closed cap on a dry shelf matters more than separation from neighbours. Nothing about it requires special segregation. Even so, place it away from acids, since it reacts with them, and keep burnt magnesium residues from demonstrations out of the stock jar. A prep room usually holds one large tub and several small ones decanted for classes. Date every tub and write the grade on the label when the supplier names one.
How to tell it has deteriorated
Caking is the telltale change. Fresh magnesium oxide is a very fine, free-running powder, but an old tub that has been opened in humid air forms hard lumps and may feel gritty or slightly damp. The powder can also stick to the inside of the lid and the thread, making the cap difficult to turn. These changes come from reaction with moisture and carbon dioxide, not from any hazard in the material. Watch for a faded label, a split tub and a missing date of receipt. Jars that have been topped up from another source or contaminated by burnt residue should be treated as mixed stock.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
It is not normally classified as hazardous, but it remains a chemical waste and needs a clear description: the grade if known, the quantity and the tub condition. It does not belong in a bin, a skip or any drain, and a prep room should not tip it out to clear shelf space. A waste transfer note covers the movement. Mixed or contaminated tubs, such as those used for burnt residue, are described as what they may contain. The specialist carrier packs it with other low hazard solids from the same collection.
| Usual EWC code, laboratory stock | 16 05 09 |
|---|---|
| Usually classed as hazardous waste | No |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: solid.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Questions
Can surplus magnesium oxide be thrown away with ordinary rubbish?
No. Even though it is not normally classified as hazardous, it is still chemical waste. Keep it out of bins and skips: it goes by specialist collection with a transfer note.
Why has our old tub turned lumpy?
Magnesium oxide slowly takes in moisture and carbon dioxide from the air, so lumps form in tubs opened often or poorly sealed. It signals a bad seal rather than a danger, but the contents are no longer pure.
Can burnt magnesium residue go back in the stock jar?
No. Residue from demonstrations makes the jar mixed stock, so a new label and a separate container are needed, and the collector describes it by what it may contain.
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