Malathion (CAS 121-75-5): storage and disposal
Dispensed as a lotion against lice and other external parasites, malathion is an organophosphate that pharmacies and veterinary practices keep in small bottles. The classification names harm if swallowed, an allergic skin reaction and very toxic effects on aquatic life with long lasting effects. The aquatic statement is the reason leaks and spills are treated seriously.
- CAS number
- 121-75-5
- Form
- Liquid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
Hazardous to the environment
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Pharmacy stock lives on a dispensary shelf and veterinary stock in the medicines cupboard, so the first check is whether the lotion is separate from food, drink and animal feed. Keep bottles upright on a tray, so a leak stays contained and cannot reach a floor drain, given the aquatic hazard. The skin sensitiser statement means nobody should handle a leaking bottle bare-handed. Date the stock on arrival and keep it in a dry, labelled and well organised store, following the product safety data sheet for temperature, ventilation and separation from ignition sources. Some malathion lotion formulations contain flammable solvents. A lotion bought for a single treatment course often sits unused for years, so check old bottles when you do stock counts.
How to tell it has deteriorated
Look at the bottle rather than the liquid: a swollen or distorted body, a sticky residue around the cap, a stained label and a cap that has crept loose all suggest a poor seal. Malathion has a strong, unpleasant odour, so any smell noticed by chance near a closed bottle or cupboard may point to a leak. Nobody should sniff a bottle to check. Any change in colour or a separated layer should be noted. Loss of the date or the dispensing record is enough to class the bottle as unwanted.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
Grouping depends on the actual product formulation, so give the product name and strength from the label. Keep bottles upright with caps sealed inside an outer container. Pouring it away, rinsing a bottle or wiping a spill into a drain is not acceptable because of the aquatic hazard, and it should not go in the general bin. The waste code depends on setting: human healthcare normally uses 18 01 09 and veterinary practices normally use 18 02 08. List bottle counts and condition.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 09 |
| Veterinary setting | 18 02 08 |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: topical lotion.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H317 May cause an allergic skin reaction.
- H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P391 Collect spillage.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why must a malathion spill never go near a drain?
The classification includes very toxic effects on aquatic life with long lasting effects. A spill must not reach a drain or watercourse. Keep people away from the affected area and report the spill to your safety lead so that trained personnel can follow the applicable spill procedure. Contaminated materials require appropriate waste classification and specialist collection.
Can a leaking malathion bottle be handled with bare hands?
No. The substance may cause an allergic skin reaction and is harmful if swallowed. Wear gloves, stand the bottle in a sealed outer container and tell the collector it has leaked.
Which waste code applies in a veterinary practice?
Veterinary stock normally uses 18 02 08, while human healthcare uses 18 01 09. If the lotion is being cleared as a discarded chemical rather than a practice medicine, the base code differs, so describe the situation when you enquire.
How old is too old for a malathion lotion bottle?
The label date and the dispensing record decide. If the date is missing, the label is unreadable or the cap has crept loose, treat it as unwanted. Do not open it to judge the contents.
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