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Chemical collection and stock control for UK schools, universities and hospitals

Menthol (CAS 2216-51-5): storage and disposal

Menthol is a crystalline solid with a penetrating minty smell, kept in school, college and university stores and in pharmacies. It causes skin irritation and serious eye irritation. Its smell travels, and its crystals have a habit of moving around a closed jar, so old stock often looks different from what was put in.

CAS number
2216-51-5
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Skin irritation and serious eye irritation are the hazards behind how it is held, and its general storage class means an ordinary dry, labelled shelf with a stock record is enough. The smell is a bigger practical issue. Menthol vapour escapes past loose caps and can taint nearby stock, particularly food grade supplies or unwrapped items in a pharmacy, so keep the lid tight and the jar apart from them. It is a low melting solid, so a warm cupboard fuses the crystals. A tray beneath the jar catches stray crystals, and goggles belong where it is weighed or decanted.

How to tell it has deteriorated

Look at the neck and cap first. Menthol crystals slowly migrate, so fresh looking crystals regrown on the inside of the lid or around the neck show that a jar has been warm and not tightly sealed. A fused mass or a solid block at the base follows warmth, and a strong mint smell in the cupboard means vapour is escaping. Labels can curl or stain where crystals have crept under them, and a cap sometimes sticks to the glass. Few other changes show. A jar with any of these features is recorded as it stands and left closed.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Write down what the container really holds before asking for a collection: label wording, grade if stated, the amount left, and whether the crystals are loose, fused or regrown at the neck. A pharmacy jar should say which shelf it came from. Waste code 16 05 06* usually applies in a lab pack, 16 05 08* to a discarded organic chemical outside one, and 18 01 06* in a human healthcare setting, though the producer classifies the waste. Specialist collection is the only route. It must not be put in general waste or a drain, and nobody should try to melt or burn leftovers.

Waste codes for Menthol
Usual EWC code, laboratory stock16 05 06*
Discarded organic chemical, not a laboratory pack16 05 08*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: crystals.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H315 Causes skin irritation.
  • H319 Causes serious eye irritation.
Precautionary statements
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P332+P317 If skin irritation occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.

Substance as classified, dilutions may differ.

Questions

Why do crystals keep appearing on the inside of our menthol jar lid?

Menthol vapour escapes the solid and settles again on cooler surfaces, which is why crystals grow at the neck and lid. It signals warmth and a loose seal. Tighten the cap and keep the jar in a cooler cupboard.

Can the smell contaminate other stock in our pharmacy store?

It can, because vapour passes through loose caps and packaging. Keep menthol in a tightly closed jar away from food grade supplies and unwrapped items, and book collection if a jar leaks smell.

Is menthol from a pharmacy handled differently from lab stock?

The route is the same, which is specialist collection. A pharmacy in a human healthcare setting usually uses the healthcare code, while a school or university usually uses the laboratory code, though the producer classifies the waste. State where it was held when booking.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C10H20O. EC number 218-690-9.

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