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Chemical collection and stock control for UK schools, universities and hospitals

Mercury(II) chloride (CAS 7487-94-7): storage and disposal

Also called mercuric chloride, this very toxic mercury salt is still found as legacy stock in school, college and university stores, and in old histology fixatives. It is fatal if swallowed, causes severe burns and can be absorbed through skin. Repeated exposure damages organs, and it is very toxic to aquatic life. Handling turns on what form it is in and what the label really says, since an old fixative may carry only a working name.

CAS number
7487-94-7
Form
Solid
Storage class
Toxic
Signal word
Danger
Usual EWC code, laboratory stock
16 05 06*
  • Corrosive pictogramCorrosive
  • Acute toxicity pictogramAcute toxicity
  • Serious health hazard pictogramSerious health hazard
  • Hazardous to the environment pictogramHazardous to the environment

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as toxic stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Acids and oxidisers have no place beside mercuric chloride: toxic stock is kept apart from both so that a spill or reaction cannot release toxic fumes. A locked cabinet with a stock record suits the solid, away from food and drink areas and out of direct light. On a histology bench the same salt may be sitting in a working fixative, which may be less hazardous than the pure solid but is never safe, and some mercury fixatives also contain chromium(VI) compounds or formaldehyde, so it deserves the same locked store and a tray to catch a leak. Solutions of this salt attack many metals, so a metal shelf, cap or instrument tray near a fixative bottle is a poor arrangement. Older school bottles may carry the name corrosive sublimate, and they belong in the same cabinet under a legible modern label.

How to tell it has deteriorated

Start with the cap and the label. A histology bottle may be a reused container with a handwritten fixative name and no mention of mercury, and that gap is often the most serious fault on it. Corroded metal closures and a white crust of dried salt around the neck both suggest a leak or evaporation, and a crust is still the toxic salt. The white solid itself shows little change with age, although light can slowly darken mercury salts, so a grey or darker surface on old stock is worth recording. It should not be read as the hazard fading. Staining around the cap, a failed seal or a missing entry in the stock record are further reasons to report the bottle and leave it closed.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a toxic laboratory pack with compatible chemicals.

Record the exact wording on the container before asking for a collection, including older names such as mercuric chloride or corrosive sublimate. Note whether it is a dry solid or a fixative solution, the container size and material, how full it is and any crust or corrosion around the closure. Those details decide how it is grouped, since this corrosive mercury salt needs a place apart from acids and oxidisers in the lab pack. The usual code depends on setting: 18 01 06* for human healthcare, otherwise 16 05 06* in a lab pack or 16 05 07* outside one, though the producer classifies the waste. Specialist collection is the only route, so it never goes into a sink, drain, general waste bin or skip, and nobody should try to treat it first. The consignment paperwork then stays on your file.

Waste codes for Mercury(II) chloride
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Do not store with

  • OxidiserToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
  • AcidToxic stock is stored apart from acids. Several toxic salts release toxic gas in contact with acid.

Named chemicals to keep apart

  • Acetic acidToxic stock is stored apart from acids. Several toxic salts release toxic gas in contact with acid.
  • Calcium hypochloriteToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
  • Hydrochloric acidToxic stock is stored apart from acids. Several toxic salts release toxic gas in contact with acid.
  • Hydrogen peroxideToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
  • Nitric acidToxic stock is stored apart from acids. Several toxic salts release toxic gas in contact with acid.
  • Potassium nitrateToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
  • Potassium permanganateToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
  • Sulfuric acidToxic stock is stored apart from acids. Several toxic salts release toxic gas in contact with acid.

Common quantities

Usually held as: legacy stock, histology fixatives.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H300 Fatal if swallowed.
  • H314 Causes severe skin burns and eye damage.
  • H317 May cause an allergic skin reaction.
  • H341 Suspected of causing genetic defects.
  • H361f Suspected of damaging fertility.
  • H372 Causes damage to organs through prolonged or repeated exposure.
  • H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
  • P203 Obtain, read and follow all safety instructions before use.
  • P260 Do not breathe dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P270 Do not eat, drink or smoke when using this product.
  • P273 Avoid release to the environment.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P316 IF SWALLOWED: Get emergency medical help immediately.
  • P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P316 Get emergency medical help immediately.
  • P318 If exposed or concerned, get medical advice.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P363 Wash contaminated clothing before reuse.
  • P391 Collect spillage.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P262 Do not get in eyes, on skin, or on clothing.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P317 Get medical help.
  • P333+P317 If skin irritation or rash occurs: Get medical help.
  • P361+P364 Take off immediately all contaminated clothing. And wash it before reuse.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.

Substance as classified, dilutions may differ.

Questions

How do we get rid of old mercury fixative from the histology bench?

Only through a specialist collection. Never pour mercury fixative or its washings into a sink or drain, and never dilute it first, because mercury(II) chloride is very toxic to aquatic life with long lasting effects. Keep it in a closed, labelled container in the locked store until it goes.

Which waste code applies in a hospital histology department?

In a human healthcare setting the List of Waste code is normally 18 01 06*, though the producer classifies the waste. Elsewhere it is normally 16 05 06* in a lab pack, or 16 05 07* for a discarded inorganic chemical outside one. Tell us the setting and the form, and state the mercury content plainly.

There are white crystals around the cap of an old fixative bottle. What now?

Assume they are mercury salt. Do not wipe them, scrape them or force the cap. Keep the bottle upright on its tray in the locked store, note what you can see, and mention the crust when arranging collection, because a leaking closure affects how the bottle is packed.

Our solid has gone darker on top. Is it less dangerous now?

No. Light can slowly darken mercury salts, but a darker surface tells you nothing good about the contents, and it is still a mercury compound with the same waste status. Keep it closed and out of the light, and record the colour change for the collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Cl2Hg. EC number 231-299-8.

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