Phenoxyethanol (CAS 122-99-6): storage and disposal
University labs, histology stores and pharmacies hold phenoxyethanol as a colourless liquid, either neat or as a preservative ingredient. Its classification as causing serious eye damage, as harmful if swallowed and as a respiratory irritant makes the neat liquid a bottle to keep below eye height, even though it looks as plain as water.
- CAS number
- 122-99-6
- Form
- Liquid
- Storage class
- General
- Signal word
- Danger
- Usual EWC code, laboratory stock
- 16 05 06*
Corrosive
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Neat bottles tend to be small, glass or plastic, and are often tucked on a shelf beside mountants and fixatives in histology or at the back of a pharmacy compounding cupboard. The serious eye damage classification is the reason for keeping them low and upright on a tray, not above bench height. Check that the cap is tight, since the vapour is a respiratory irritant, and keep the date of receipt on the label. A bottle labelled as a preservative may be a made-up product and should be recorded as it is printed, not assumed to be neat. Keep it away from open benches and from food, and group it with general liquid stock, not with acids.
How to tell it has deteriorated
This liquid gives few visible signs. It is normally a clear, colourless, slightly oily liquid and nothing about the name or the condition suggests a particular chemical change with age, so the container carries the evidence. Look for a bottle that is lower than it should be, a dried residue or sticky film at the neck, a cracked or softened plastic bottle, a stained or peeling label, and rings on the shelf under it. A cap that smells of the liquid when you walk past shows it is not sealing. Any bottle with no date or a label you cannot read should be listed rather than guessed at.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
How it is grouped and packed depends on whether it is neat. A bottle of the neat liquid is listed with its volume and packed with other compatible organic liquids in sealed UN approved packaging, while a preservative product is listed by the name on its label. The usual code in a university is 16 05 06*, and 18 01 06* in a pharmacy or other human healthcare setting. The eye damage classification means that bottles with damaged caps are described carefully. It does not go to a sink or the general bin, and it is not for diluting or treating. A registered carrier collects it.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: neat, preservative.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H318 Causes serious eye damage.
- H335 May cause respiratory irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P319 Get medical help if you feel unwell.
- P330 Rinse mouth.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Is neat phenoxyethanol the same waste as a preservative product containing it?
Not necessarily. The classification applies to the substance, and a made-up preservative may be less hazardous. List the product by the name on its label and let collection staff confirm the entry.
How long does phenoxyethanol keep on the shelf?
The applicable shelf life depends on the product and supplier information. Neat phenoxyethanol may show few visible signs of deterioration. Check the label, supplier expiry or retest information and container condition. An intact bottle alone does not establish that the contents remain suitable for use.
Why is the bottle kept low?
It is classified as causing serious eye damage, so a splash from a high shelf matters more than for many general liquids. Keep it upright on a tray at a low height, away from open benches.
What do we do with a small leftover of phenoxyethanol?
Leftover liquid is chemical waste and never goes down a sink. Keep it in a labelled container, describe it accurately, and arrange specialist collection. Do not dilute it or treat it first.
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