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Chemical collection and stock control for UK schools, universities and hospitals

Potassium bromide (CAS 7758-02-3): storage and disposal

Potassium bromide is a white crystalline salt kept in school, college and university stores and in some veterinary practices. It is classified as causing serious eye irritation and carries a Warning signal word. The classification is modest, but stock still needs to be described accurately, and what it sits beside on the shelf matters more than the salt does.

CAS number
7758-02-3
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Oxidising chemicals and strong oxidising acids are the neighbours to avoid, since either can free brown bromine vapour from a bromide, so do not keep the tub on a shelf with them. A dry general shelf is otherwise enough. Dust is the practical hazard: because it causes serious eye irritation, wear eye protection when scooping and close the lid afterwards. University labs often keep a tub for pressing infrared discs, and veterinary practices may hold it as part of treatment for dogs with epilepsy, so labels should show the source and date of receipt. A tub of white salt looks like many others, so write the full name clearly.

How to tell it has deteriorated

A white, free flowing salt is what to expect. Damp makes it cake into lumps, and a tub in a humid store may have set solid. It gives few distinctive signs of its own, so the container carries the evidence: a faded or lifted label, a cracked tub, a stained cap and no date of receipt. A yellow or brown tinge or an unusual odour is not normal for this salt and may indicate contamination. Do not open a suspect container to investigate or attempt to close one that may be reacting. Record observations that can be made safely and request specialist advice.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Grouped in a lab pack with compatible solids, potassium bromide is kept away from oxidisers and acids for the same reason it is on the shelf. Waste code 16 05 06* is the usual entry, with 18 02 05* for a veterinary setting, or generally 18 02 08 for a licensed veterinary medicine, so say which kind of holder it came from and whether it is a medicine. It does not go into a sink, a drain, a general waste bin or a skip, however mild it looks, and staff should not try to treat it first. Record the container size, how much is left, whether it has caked and whether any is in a dispensing pot from a veterinary treatment room.

Waste codes for Potassium bromide
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Veterinary setting18 02 05*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: solid.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H319 Causes serious eye irritation.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P271 Use only outdoors or in a well-ventilated area.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P319 Get medical help if you feel unwell.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P332+P317 If skin irritation occurs: Get medical help.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Why keep potassium bromide away from oxidisers?

Oxidising chemicals or strong oxidising acids can free brown bromine vapour from a bromide. Keep the tub on a separate shelf from oxidising and acid stock, in a dry, labelled store.

What hazards does the classification cover?

Serious eye irritation, with a Warning signal word. No other hazard is listed, but it remains a chemical waste, so wear eye protection while handling and never put surplus in the bin.

Can a vet practice dispose of leftovers with clinical waste?

No. Leftover potassium bromide goes by specialist collection, using the veterinary waste code where it applies. It is not put in clinical or general waste, a sink or a drain.

Why has the tub turned yellow?

A yellow or brown tinge is not normal for this salt. It can indicate contamination, including contact with an oxidising chemical. Leave the container undisturbed, record what is nearby if this can be done safely, and report it for specialist assessment. Do not open or rework the stock.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula BrK. EC number 231-830-3.

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