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Chemical collection and stock control for UK schools, universities and hospitals

Potassium dihydrogen phosphate (CAS 7778-77-0): storage and disposal

Held as buffer stock in school, college and university stores and in pathology and histology labs, potassium dihydrogen phosphate is a white crystalline salt. It is not classified as hazardous on the sources we checked, but it remains a chemical waste that must be described accurately. Most of the problems come from damp and from old solutions made from it, and not from the salt itself.

CAS number
7778-77-0
Form
Solid
Storage class
General
Usual EWC code
16 05 09

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

A quick check that costs nothing: pick up the tub and see whether the salt moves. If it rattles loose, the lid has been doing its job. Keep it in a dry, labelled, well organised store, dated on arrival, with the full name on the label, since the monobasic and dibasic phosphates are easy to swap. Histology and pathology labs usually hold both and should shelve them apart. Food grade supplies stay separate from laboratory stock. It is not classified as hazardous on the sources we checked, so no cabinet is needed, but a stock record still applies.

How to tell it has deteriorated

The salt itself keeps well, so the first change is caking: a tub that has taken up damp sets into a hard lump at the base, and a crust forms around the neck. Buffer solutions made from phosphate are a different matter, because a cloudy bottle, floating threads or mould on the surface show the liquid has stood too long. This substance gives few other distinctive signs. Faded labels, a cracked tub and an unknown date of receipt are the remaining checks. Each is recorded as found, and old solutions are listed separately from dry stock.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Hospital and pathology holders would use 18 01 07, while a school or university holder would use 16 05 09, which is the waste code for this item as a non-hazardous chemical. The distinction is the setting, so say where it came from. Not being classified as hazardous on the sources we checked does not make it a sink or bin item: it never goes down a drain, into general waste or a skip, and staff should not try to treat it first. Dry salt and any solutions are described and packed separately. Record the size, quantity and condition.

Waste codes and transport details for Potassium dihydrogen phosphate
EWC code, laboratory chemicals16 05 09
Human healthcare setting18 01 07
Hazardous wasteNo

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: buffer stock.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Questions

Is potassium dihydrogen phosphate hazardous?

It is not classified as hazardous on the sources we checked, so a waste transfer note applies. It is still a chemical waste that must be described accurately and collected by the specialist route.

Can old buffer solutions be kept?

A cloudy or mouldy bottle shows the buffer has stood too long. Record it as an old solution, keep the cap on and list it for collection separately from the dry salt.

How do I avoid mixing up the monobasic and dibasic salts?

Write the full name on each label, date it, and shelve the two apart. The abbreviations are easy to mix up, particularly in a histology or pathology store holding both.

Which waste code applies to a hospital lab?

A human healthcare setting may use 18 01 07, and a school or university lab 16 05 09. Say which setting the stock sits in when you ask for collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula H2KO4P. EC number 231-913-4.

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