Potassium oxalate (CAS 583-52-8): storage and disposal
Potassium oxalate monohydrate is a white crystalline salt kept in school and college stores, university labs and pathology departments, where it is also known as a blood sample additive. It is classified as harmful if swallowed and in contact with skin, and as causing serious eye irritation. Its source, loose reagent or additive stock, decides how the waste is described.
- CAS number
- 583-52-8
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
On a school prep room shelf the tub of potassium oxalate tends to sit with the other oxalates and white salts bought for qualitative tests, and the risk is mistaking one for another. Name it in full on the label and date it on arrival. A dry, well organised store suits a general class chemical. Harm by swallowing and skin contact means gloves are sensible, and serious eye irritation means eye protection when scooping. Pathology and university stores that hold it as an additive keep it with their own stock records, away from food and drink areas and from acid stock.
How to tell it has deteriorated
What a technician sees first is a tub with white crystals that move freely. The monohydrate can take up damp and cake into lumps, and a lid left loose lets dust into the crystals. The salt gives few distinctive signs of its own, so judge the container: a faded or lifted label, a crusted neck, a cracked tub or a missing date of receipt. A tub that has been decanted into a smaller unmarked pot is recorded as it is found. If the contents have changed colour or smell, close the lid, describe what you can see and report it.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Waste code 16 05 06* is the usual entry for a school or university holder. Where it is a discarded organic chemical outside a laboratory pack, 16 05 08* applies, and a human healthcare setting such as a pathology lab would use 18 01 06*. Say which fits. It never goes into a sink, a drain, a general waste bin or a skip, and staff should not try to treat it first. The record should say whether it is loose crystal or additive stock, the container size and how much is left. Blood tubes are a different matter and are not covered by a chemical collection.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: monohydrate, blood tube additive.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H302 Harmful if swallowed.
- H312 Harmful in contact with skin.
- H319 Causes serious eye irritation.
Precautionary statements
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why is it used as a blood tube additive?
It is a salt used in some sample tubes to stop blood clotting. For waste purposes, loose potassium oxalate is described as the chemical it is, with its source and the quantity, whichever setting it comes from.
What hazards does the classification list?
Harmful if swallowed, harmful in contact with skin and serious eye irritation, with a Warning signal word. Use gloves and eye protection, and keep it away from food and drink areas.
Which waste code do we use in a pathology lab?
A human healthcare setting may use 18 01 06* instead of 16 05 06*. Say whether the stock sits in a hospital pathology lab or a university lab when you ask for collection.
Our tub has gone lumpy. Is it a problem?
Damp has caked the crystals. Keep the lid tight, record the tub as caked and list it for collection. Do not break the lumps up, and do not dry them out.
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