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Chemical collection and stock control for UK schools, universities and hospitals

Potassium thiocyanate (CAS 333-20-0): storage and disposal

Potassium thiocyanate is a colourless crystalline salt kept in school, college, university and pathology stores, best known for the blood red colour it gives with iron. It is classified as harmful if swallowed, in contact with skin and if inhaled, as causing serious eye damage, and as harmful to aquatic life. Its tendency to soak up moisture is the first thing a technician sees.

CAS number
333-20-0
Form
Solid
Storage class
General
Signal word
Danger
Usual EWC code, laboratory stock
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Harm by three routes, swallowing, skin contact and inhalation, together with serious eye damage, decides how it is handled: eye protection, gloves and a lid that goes back on straight away. Keep it away from acids, which can release toxic gas from a thiocyanate, from bleach and other strong oxidisers, which can also give toxic gases, and away from anything it could be confused with on a shelf of white salts. A dry, labelled, well organised store is the baseline. School and college stores that kept it for the iron test should check that a tub from years ago still has a readable label and a date of receipt.

How to tell it has deteriorated

It takes up water from the air, so the first sign on old stock is crystals that have clumped, turned wet or run together into a damp mass at the base. A tub left open may hold a pool of liquid, with a sticky crust at the neck and a stained label. The salt gives few other distinctive signs, so also check for a cracked tub, corroded cap, faded writing and a missing date. A wet tub is harder to handle safely and should be recorded as damp, and reported, instead of being dried or emptied.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

A pathology store in human healthcare would use 18 01 06*, while a school or university holder would use 16 05 06*, or 16 05 07* for a discarded inorganic chemical outside a lab pack. Acids are kept out of the same box, for the reason they are kept off the shelf. It is never poured into a sink or drain or put in general waste or a skip, and staff should not try to dry or treat it. Record the container size, how much is left, and whether the contents have gone wet or run into liquid.

Waste codes for Potassium thiocyanate
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: solid.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H312 Harmful in contact with skin.
  • H318 Causes serious eye damage.
  • H332 Harmful if inhaled.
  • H412 Harmful to aquatic life with long lasting effects.
  • EUH032 Contact with acids liberates very toxic gas.
Precautionary statements
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P271 Use only outdoors or in a well-ventilated area.
  • P273 Avoid release to the environment.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P317 Get medical help.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P337+P317 If eye irritation persists: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P391 Collect spillage.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Why is my potassium thiocyanate wet?

It absorbs moisture from the air and can run into a damp mass or liquid. Close the lid, record it as damp and report it for collection. Do not try to dry it out or empty the tub.

What is it classified as?

Harmful if swallowed, in contact with skin and if inhaled, causing serious eye damage, and harmful to aquatic life with long lasting effects. Use eye protection and gloves and keep the lid closed.

Why keep it away from acids?

Acids can release toxic gas from a thiocyanate, so keep the tub on a separate shelf from acid stock, and keep the two out of the same box or tray when moving stock.

Is the paperwork different for a pathology lab?

It can be. A human healthcare setting may use waste code 18 01 06* instead of 16 05 06*, so say whether the stock sits in a hospital or pathology store when you ask for collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula CKNS. EC number 206-370-1.

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