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Chemical collection and stock control for UK schools, universities and hospitals

Rochelle salt (CAS 6381-59-5): storage and disposal

Also called potassium sodium tartrate tetrahydrate, Rochelle salt is a crystalline solid held in school and college prep rooms and university labs, often for crystal growing and carbohydrate tests. It is not classified as hazardous on the sources we checked, but it remains a chemical waste and has to be described accurately. Collection follows the specialist route.

CAS number
6381-59-5
Form
Solid
Storage class
General
Usual EWC code
16 05 09

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

On a school prep room shelf this tetrahydrate usually sits in a plain tub among the salts kept for crystal growing and carbohydrate tests. General stock rules apply: a dry, labelled, well organised store, with each tub dated on arrival. It is not classified as hazardous on the sources we checked, so it can share a cupboard with other general stock, but food grade supplies kept in the same room should be separated from laboratory stock. Keep the lid screwed down so that damp air and dust stay out, and write the full name on the label, since Rochelle salt is easily mistaken for other white sodium and tartrate salts on a crowded shelf. College and university stores often hold it alongside many similar crystalline reagents, so a clear label counts for more here than any special precaution.

How to tell it has deteriorated

A good tub holds loose, clear to white crystals. Damp air can clump them together or leave a wet film inside the container, and a tub that has spent years in a humid store may have set into a hard cake. This substance gives few distinctive signs of its own, so the general checks do most of the work: caking, clumping, a change in colour or smell, a faded label and no date of receipt. A solution kept in a bottle is a separate problem, since a cloudy or mouldy liquid shows it has stood far too long. Whatever the condition, it is described as it is found, and old or damp stock does not change the route.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Do not wash it down a sink or drain, put it in a general waste bin or skip, or try to treat it first, even though it is not classified as hazardous on the sources we checked. It stays a chemical waste and has to be described accurately. Waste code 16 05 09 is the entry held for it, and the paperwork is a waste transfer note, not a hazardous waste consignment note. Collection is by specialist route, with the tub packed in a lab pack with compatible stock. Record the full name, the tetrahydrate form, the quantity and whether it is a solid or a solution. Stock that has caked or gone damp is described as it is.

Waste codes and transport details for Rochelle salt
EWC code, laboratory chemicals16 05 09
Hazardous wasteNo

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: tetrahydrate.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Questions

Is Rochelle salt classed as hazardous waste?

It is not classified as hazardous on the sources we checked, so a waste transfer note applies. It is still a chemical waste that must be described accurately, and it goes by specialist collection, not into a sink, drain, general waste bin or skip.

Why does a school still need a collection for it?

Because a low hazard chemical is still a chemical waste. It cannot be treated by staff or put in the bin. Specialist collection takes it in a lab pack and the waste is described under the Duty of Care.

Can old Rochelle salt crystals still be kept?

Loose crystals in a dry, labelled tub can stay on the shelf. Caked, damp or undated stock is better recorded and collected, and any solution that has turned cloudy or mouldy should be listed for collection too.

Does it need a locked or separate cabinet?

Not on the sources we checked. General stock rules apply: a dry, labelled, well organised store with the date of arrival written on the tub, and with food grade supplies kept apart from laboratory stock.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C4H12KNaO10.

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