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Chemical collection and stock control for UK schools, universities and hospitals

Sodium dihydrogen phosphate (CAS 7558-80-7): storage and disposal

Mono and disodium phosphate jars sit side by side on buffer shelves in schools, colleges, universities, pathology and histology labs, and sodium dihydrogen phosphate is the acidic half of the pair. It is not classified as hazardous on the sources we checked, but it is still a chemical waste. A mix-up between the two jars is the failure that causes real trouble.

CAS number
7558-80-7
Form
Solid
Storage class
General
Usual EWC code
16 05 09

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

The shelf decides how this stock goes wrong. Sodium dihydrogen phosphate and disodium hydrogen phosphate are usually kept in identical white tubs, so every label needs the full name and the date written clearly, and the two should have a gap between them. Keep the buffer stock in a dry, labelled, well organised store, away from food grade supplies. Histology and pathology labs often keep made-up buffer in bottles next to the dry salts, and these should be marked with the date and who made them. It has no particular chemical partners to separate it from.

How to tell it has deteriorated

Look first at what the powder is doing in the tub. Hard lumps or a damp cake show that moisture has entered, and the usual cause is a cap left loose. Made-up buffer bottles may turn cloudy or grow a film or floating threads, and they should not be used again. Faded handwriting on a decanted tub is the commonest real problem. Beyond these changes the salt shows few visible signs. A tub that has been topped up from another jar counts as mixed stock, and an undated jar is simply old.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

The waste code is for a non-hazardous chemical, so a waste transfer note applies and healthcare holders use their healthcare entry. It is not classified as hazardous on the sources we checked, but it remains chemical waste that must be described accurately, so the buffer stock does not go into a sink, a bin or a skip. List the dry salt and any made-up buffer separately, and give the quantity and the label state. Buffer bottles with unknown contents are described as unknown liquid. The carrier packs low hazard solids together.

Waste codes and transport details for Sodium dihydrogen phosphate
EWC code, laboratory chemicals16 05 09
Human healthcare setting18 01 07
Hazardous wasteNo

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: buffer stock.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Questions

Does old phosphate buffer need specialist collection?

Yes. Although not classified as hazardous on the sources we checked, buffer is still chemical waste. It must not go down a sink, and bottles are listed with a clear description and date.

How do we stop mixing it up with the disodium salt?

Write the full name on both labels, store them apart and check the label every time. They are different chemicals even though the tubs look the same.

What does a cloudy buffer bottle mean?

Contamination or growth has probably occurred, and the buffer is no longer reliable. Do not use it for any further work, label the bottle clearly with the date and arrange collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula H2NaO4P. EC number 231-449-2.

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