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Chemical collection and stock control for UK schools, universities and hospitals

Sodium metabisulfite (CAS 7681-57-4): storage and disposal

Sodium metabisulfite is a white solid held as a reducing agent and sulfite preservative in school and college stores, university labs, histology rooms and some pharmacy stock. Its classification covers harm if swallowed and serious eye damage, so it is handled as hazardous waste. What decides collection is how well the container has kept damp and acid out.

CAS number
7681-57-4
Form
Solid
Storage class
General
Signal word
Danger
Usual EWC code
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

Usually a tub or glass jar of white powder or small crystals, this solid belongs on the general shelf only if that shelf is dry and well away from acids. A reaction with acid gives off sulfur dioxide, a sharp smelling gas, so keep the jar apart from acid stock in a prep room cupboard. Oxidising stock stays on a separate shelf too, because a sulfite is a reducing agent and the two should not share space. Histology and pharmacy holders tend to keep small amounts, while a school may have one old tub. Screw the cap down firmly after each use, date it on arrival and keep it off the floor where damp collects. Eye protection matters whenever it is handled, since the classification includes serious eye damage.

How to tell it has deteriorated

Left in a loosely closed jar, the powder slowly takes up oxygen and turns to sulfate, so the sharp smell fades and the stock loses its value as a reducing agent. Damp speeds this up and sets the powder into hard lumps or a solid cake at the base of the tub. Look too for a crust around the neck, a corroded metal cap, a cracked jar and a label that has faded or lifted. An old tub that gives off a strong sulfur smell on opening should be closed again straight away and reported. A pharmacy or histology jar with no date of receipt is treated as old stock, because nothing on the shelf shows how long the cap has been loose.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.

Waste code 16 05 06* is the usual entry for this item, and the asterisk marks it as hazardous waste. A pharmacy or hospital store would use 18 01 06* instead, so say which setting the jar comes from. It does not go into a sink, a drain, a general waste bin or a skip, and nobody should try to treat it first. The powder travels in a lab pack with compatible stock and never beside acids, which matters more than the paperwork, since a leaking jar next to acid bottles would give off sulfur dioxide in transit. Record each container size and whether the seal is intact, and say if the powder has set into a lump. A consignment note is completed for the collection.

Waste codes and transport details for Sodium metabisulfite
EWC code, laboratory chemicals16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Hazardous wasteYes

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Common quantities we collect

Usually held as: solid.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H318 Causes serious eye damage.
Precautionary statements
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P317 Get medical help.
  • P330 Rinse mouth.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

How should unwanted sodium metabisulfite be disposed of?

By specialist collection. It is classified as harmful if swallowed and as causing serious eye damage, and it is treated as hazardous waste. Not into a sink, drain, general waste bin or skip, and staff should not treat it first.

Why must it be kept away from acid stock?

Acid reaching a sulfite releases sulfur dioxide, a sharp smelling gas that is unpleasant in a small prep room. Store it on a shelf apart from acids, and keep a spilt jar away from acid bottles while it waits for collection.

How do I know if an old jar has gone off?

Caking, hard lumps, a faded smell, a crusted neck or a corroded cap all point to age. The powder oxidises to sulfate over time, so old stock may no longer work as a reducing agent even though it remains a chemical waste.

Does a pharmacy or histology lab use different paperwork?

The waste is still described accurately and a consignment note still goes with it. A human healthcare setting may use waste code 18 01 06* rather than 16 05 06*, so say which setting the stock sits in when you ask for collection.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Na2O5S2. EC number 231-673-0.

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