Sulfanilic acid (CAS 121-57-3): storage and disposal
Sulfanilic acid is held as an off-white crystalline solid in school and college prep rooms, university labs and pathology stores. It causes skin irritation and serious eye irritation, and may cause an allergic skin reaction. Because it is a skin sensitiser, a jar that gets handled again and again is a bigger concern than one that is opened once, and that shapes how it is held and cleared.
- CAS number
- 121-57-3
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
The hazard that decides where it goes is the allergic skin reaction. A jar of sulfanilic acid should sit in a dry, labelled, well organised store, with the lid on firmly, and nobody should be reaching into an open tub with bare hands. School stores keep it for azo dye work, and pathology stores may hold it for nitrite testing, so it often sits alongside coloured reagent bottles that look similar. Label it clearly and date it on arrival. Keep food grade supplies away from it, and keep the jar out of food and drink areas.
How to tell it has deteriorated
Few visible signs of age show up here, so the container tells the story. Crystals that have clumped or caked suggest damp. A loose or cracked lid, powder on the outside of the jar or on the shelf, a faded or stained label and an unknown date of receipt are the typical faults. Coloured dust from neighbouring reagent bottles can make a jar look dirty. Powder on the shelf is the sign most worth acting on, because the hazard is a sensitiser. A jar that is dusty, undated or unlabelled should be left closed and listed for collection.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
Say on the booking that it may cause an allergic skin reaction, so that whoever packs the load knows what the powder is. Record whether the jar holds loose crystals or caked lumps, how much is left and whether dust has escaped onto the outside. It is an organic chemical, so a discarded jar that is not in a lab pack usually takes 16 05 08*, and a healthcare setting such as a pathology department usually uses 18 01 06*, and the producer confirms the classification. It must never be tipped into a sink or drain or put in a bin or skip, and it must not be dissolved or neutralised first.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: solid.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H315 Causes skin irritation.
- H317 May cause an allergic skin reaction.
- H319 Causes serious eye irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why does a skin sensitiser need different handling from an irritant?
Repeated skin contact can lead to an allergic reaction. Sulfanilic acid may cause one, so keep the lid on, avoid bare hands in an open jar and list old stock for collection rather than opening it to look.
What does powder on the outside of the jar mean?
Solid has escaped from a loose or dirty lid. Do not wipe it carelessly. Keep the jar closed and upright on its shelf, tell the collector about the powder and list it with the amount left.
Does it need a different code in a pathology department?
Usually. A human healthcare setting normally uses 18 01 06*, while a discarded organic chemical outside a lab pack in a school or college normally uses 16 05 08*, and the producer confirms the classification. Tell the booking team which setting the jar came from.
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