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Chemical collection and stock control for UK schools, universities and hospitals

Tannic acid (CAS 1401-55-4): storage and disposal

Tannic acid is held as a pale brown powder in school and college prep rooms, university labs and histology departments. It causes serious eye irritation. It is a natural plant extract that darkens in air and light, and it stains blue-black with iron salts, so an old tub shows its age in colour and in marks on the shelf.

CAS number
1401-55-4
Form
Solid
Storage class
General
Signal word
Warning
Usual EWC code, laboratory stock
16 05 06*
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

Serious eye irritation is what decides handling, so the lid should stay on firmly to keep dust out of the air, and the tub should not sit on a high shelf. Keep it in a dry, labelled, well organised store, dated on arrival, and apart from food grade supplies. Iron salts are the practical thing to separate, because tannic acid stains blue-black on contact with iron, so spilt powder near iron(II) or iron(III) stock can mark the shelf. Light and air darken it, so a window shelf is a poor place. Histology stores should keep it in its labelled container.

How to tell it has deteriorated

Pale yellow-brown powder is normal, and the first change to look for is darkening. Tannic acid is oxidised by air and light, so an old tub goes darker, and a tub that has taken up damp may clump or set. Blue-black marks on a shelf or a lid point to contact with iron. Also check for a loose or cracked lid, powder on the outside, a faded label and an unknown date of receipt. A tub that has darkened, caked or stained its shelf is still the same chemical waste, and should stay closed and be listed for collection.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

A bin or a skip is not the place for it, and it must never go into a sink or drain, where it would stain. It must not be dissolved or neutralised first either. Tannic acid is organic, so a discarded tub outside a lab pack usually takes 16 05 08*, and 18 01 06* usually applies in a healthcare setting such as a histology department, and the producer confirms the classification. Record the colour of the powder, the amount left and whether the lid has failed. The collector groups it with other organic solids and keeps it away from iron salts, which is why those should be itemised separately on your inventory.

Waste codes for Tannic acid
Usual EWC code, laboratory stock16 05 06*
Discarded organic chemical, not a laboratory pack16 05 08*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: solid.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H319 Causes serious eye irritation.
Precautionary statements
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P337+P317 If eye irritation persists: Get medical help.

Substance as classified, dilutions may differ.

Questions

Why has our tannic acid gone dark brown?

It is oxidised by air and light, so an old, often opened tub darkens. The change is ageing and does not remove the eye irritation hazard. Keep the lid on, record the colour and list the tub for collection.

Why does it leave blue-black marks on the shelf?

Tannic acid reacts with iron salts to give blue-black staining. Keep it away from iron compounds and check whether a neighbouring jar has leaked before listing the tub for collection.

Is tannic acid from a school science store treated as hazardous waste?

Yes. It is classified as causing serious eye irritation, so it is described as hazardous waste. It must not go into a bin, sink or drain and goes by specialist collection with an accurate description.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula C76H52O46. EC number 226-562-9.

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