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Chemical collection and stock control for UK schools, universities and hospitals

Tin(II) fluoride (CAS 7783-47-3): storage and disposal

Stannous fluoride is a white solid, held in small amounts in university inorganic stores and in dental settings where it is the base of fluoride preparations. It is classified as harmful if swallowed, as a skin irritant and as causing serious eye damage. Those hazards, plus the setting it comes from, decide the waste code and how the jar is described when collection is booked.

CAS number
7783-47-3
Form
Solid
Storage class
General
Signal word
Danger
Usual EWC code, laboratory stock
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant

What to do this week

  1. Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
  3. If you no longer need it, add it to your disposal list so it can be included in a collection.

Safe storage in a school or lab

In a university chemistry store the jar usually ends up on a general shelf among the inorganic salts, which is acceptable only if it is labelled, dated and kept out of reach of casual handling. Serious eye damage is the hazard to plan around, so goggles belong beside the shelf and the container should never be decanted into unlabelled pots. In a dental surgery the bulk powder wants a separate spot from finished patient products, with a stock record, and well away from food and drink areas. Tin in this compound slowly oxidises, so keep the container tightly closed and dry, and keep it away from acids, because fluorides can release hydrogen fluoride on contact with strong acid.

How to tell it has deteriorated

Fresh powder is white and free flowing. What a technician sees first on an old jar is caking, a dull yellowish or grey tint, or hard lumps that no longer break up. Tin in the compound oxidises over time, and damp speeds that along, so a jar that has been opened often or kept somewhere humid shows it soonest. Other things to check are a label faded beyond reading, powder stuck in the thread of the cap and a jar with no record of its receipt. There are few dramatic signs with this solid. Anything that is changed in colour, wet or unlabelled is recorded as such and left closed.

How it is disposed of

We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.

Before asking for a collection, write down what the container actually carries: the name as labelled, roughly how much remains, whether it is still sealed and where it was held. A dental surgery or other human healthcare setting normally uses 18 01 06*, while a university store normally uses 16 05 06*, though the producer classifies the waste. It is packed with compatible solids in a lab pack. Washing the powder away, adding it to clinical waste or trying to make it safe on site are all ruled out. Specialist collection is the only way it leaves.

Waste codes for Tin(II) fluoride
Usual EWC code, laboratory stock16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Usually classed as hazardous wasteYes

The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.

Common quantities

Usually held as: dental preparations.

Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H315 Causes skin irritation.
  • H318 Causes serious eye damage.
Precautionary statements
  • P234 Keep only in original packaging.
  • P260 Do not breathe dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P270 Do not eat, drink or smoke when using this product.
  • P273 Avoid release to the environment.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P316 IF SWALLOWED: Get emergency medical help immediately.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • P302+P352 IF ON SKIN: Wash with plenty of water.
  • P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P316 Get emergency medical help immediately.
  • P317 Get medical help.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P332+P317 If skin irritation occurs: Get medical help.
  • P362+P364 Take off contaminated clothing. And wash it before reuse.
  • P363 Wash contaminated clothing before reuse.
  • P390 Absorb spillage to prevent material damage.
  • P391 Collect spillage.
  • P405 Store locked up.
  • P406 Store in corrosive resistant container with a resistant inner liner.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

Substance as classified, dilutions may differ.

Questions

Our dental surgery has an old tub of stannous fluoride. Which waste code applies?

A human healthcare setting normally uses 18 01 06* for this solid, and a university store would use 16 05 06*. You remain responsible for classifying the waste and the collection team can advise from what you describe, so give the label name, the amount left and where the tub was kept.

Does tin(II) fluoride lose quality when kept for years?

Yes, in the sense that the tin slowly oxidises, and damp makes that faster. Old stock tends to cake or change tint. That matters for use more than for storage, and it is no reason to open or test the jar before collection.

Can the powder go in with our clinical waste because the quantity is small?

No. A small quantity is still a chemical waste with eye damage and swallowing hazards, and it needs describing accurately. It goes by specialist collection, kept apart from the clinical and sharps streams.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula F2Sn. EC number 231-999-3.

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