Tricaine methanesulfonate (CAS 886-86-2): storage and disposal
Zebrafish and aquarium facilities in universities, and veterinary practices treating fish, hold tricaine methanesulfonate as a water-soluble white powder, used as a fish anaesthetic and often called by a supplier code on the jar. It is classified as causing skin irritation, serious eye irritation and respiratory irritation. Powder jars on a fish room shelf are the usual stock.
- CAS number
- 886-86-2
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Fish rooms are damp, so the first check at the shelf is the lid. The powder is water soluble, which means a humid room and a loose cap will clump it. Keep the jar tightly closed in a dry cupboard, away from tank water, wet benches and spray from the water system. Keep it out of reach of the stock tanks and apart from food and fish feed. Because the classification includes respiratory irritation, avoid raising dust when scooping. Label any made-up stock solution with the date and the strength, and keep it separate from the powder. A jar with no date goes on the list.
How to tell it has deteriorated
Fresh powder is white and free-flowing. Clumping or a hard cake means damp has entered the jar, and a jar kept in a fish room can take in moisture quickly. Yellowing or browning of the powder, and of made-up stock solution, is what aquarium staff watch for, and discoloured stock is usually discarded. Beyond that, check for a perished lid, powder on the outside of the jar or the shelf, a label made illegible by splashes, and a jar with no date. Little else changes in this salt. Any caked, discoloured or unlabelled jar belongs on the collection list.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Begin by recording what is in each container: dry powder in its original jar, or made-up stock solution, with the date made and the volume. Fish rooms drain to water systems, so it is worth saying plainly that unwanted solution is not tipped into a tank, a drain or a sink. A university uses 16 05 06*, and a veterinary practice 18 02 08 in the code list. The paperwork follows the hazardous route. Powder and solution are listed as separate items, and a registered carrier collects them in compatible groups. Nobody should try to treat spent solution first.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Veterinary setting | 18 02 08 |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: fish anaesthetic.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H315 Causes skin irritation.
- H319 Causes serious eye irritation.
- H335 May cause respiratory irritation.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P271 Use only outdoors or in a well-ventilated area.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
What happens to leftover anaesthetic solution from the fish room?
Leftover solution is chemical waste and is never tipped into a drain, tank or sink. Keep it in a labelled container with the date made, and list it with the powder for specialist collection.
Why has our tricaine powder gone hard?
Moisture has entered the jar, which is common in a humid fish room. Caking itself is not a hazard change, but it shows the cap is not sealing. Keep the jar closed, record it and list it if it is old.
What does discoloured stock mean?
Yellowing or browning of the powder or solution is what aquarium staff treat as a sign it is no longer sound. Do not use or treat it. Label it and list it for collection.
Is the powder classed differently from the solution?
The classification applies to the substance, and a dilute solution may be less hazardous. List them separately, with the strength and volume for the solution, and describe the product by its label.
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