Triethylene glycol dimethacrylate (CAS 109-16-0): storage and disposal
Thin, clear and easily mistaken for a plain solvent, triethylene glycol dimethacrylate is the diluting monomer in many dental resin systems, held as a component bottle in a surgery store. Its single classification is that it may cause an allergic skin reaction, so the practical risk for staff is repeated skin contact, not a single obvious spill.
- CAS number
- 109-16-0
- Form
- Liquid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code, laboratory stock
- 16 05 06*
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
Keep each component bottle separate from the thick resins and bonding agents it is mixed with, so a surgery does not end up with half-labelled pots of unknown liquid. Store it in a closed cupboard, away from the curing lamp, daylight and sources of heat, upright in a small tray, with the date of receipt on the label. Because the only classification is skin sensitisation, the habit that counts is careful handling of drips and wiped bottles, and keeping suitable gloves in the cupboard, because methacrylate monomers can pass through thin disposable gloves. Decanted or syringed amounts should carry the name, not an abbreviation that only one dental nurse understands.
How to tell it has deteriorated
A thin, clear, colourless liquid is normal, and it moves freely, much like a light oil. As a methacrylate it can begin to set, so thickening, a hazy look, specks, or a rubbery plug in the neck are the visible signs of a bottle on the way out. Resin-like residue on the dropper or cap, and a cap that sticks, say the same thing. A bottle that has changed shape, feels warm or has set solid should not be opened. Faded labels and a missing date are the other checks, and a bottle that has lost its date is best listed for collection.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in a general laboratory pack with compatible chemicals.
Leaving the surgery, it travels as a described organic liquid, so list the bottle by its printed name, the volume left and whether it has thickened. A dental surgery in a human healthcare setting normally uses 18 01 06*, and the general entry is 16 05 06*. The paperwork follows the hazardous route. Unwanted monomer is not allowed to set in the bottle on purpose, washed into a sink, put in a clinical sharps container or added to general waste. It is collected by a registered carrier and packed with other compatible organic liquids in sealed UN approved packaging.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Common quantities
Usually held as: dental resin component.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H317 May cause an allergic skin reaction.
Precautionary statements
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P333+P317 If skin irritation or rash occurs: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Is this a hazardous waste if it is only a sensitiser?
The classification is for an allergic skin reaction, and the chemical waste route and paperwork still apply. It is described as hazardous waste for collection, not placed in general or clinical waste.
How can we tell the bottle has started to set?
Look for thickening, a hazy appearance, specks, a rubbery plug in the neck, or resin crust on the cap. Do not open a bottle that is warm or misshapen. List it for collection with that description.
What should we do with leftover monomer once the resin kit is finished?
Flushing it away is not acceptable. Keep leftover monomer in the labelled bottle, record the volume, and arrange specialist collection with the rest of the dental chemical stock.
Does it need to be kept apart from other resin components?
Yes, store each component in its own labelled place so bottles are not mistaken for each other. Keep them away from heat, daylight and the curing lamp, and upright in a tray.
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