Zinc carbonate (CAS 3486-35-9): storage and disposal
Zinc carbonate is a fine, white to off-white powder that school, college and university stores hold for practical work on metal salts and thermal decomposition. It is classified as very toxic to aquatic life and as toxic to aquatic life with long lasting effects. There is no skin or eye hazard listed, so the question for a technician is mainly what it reaches, not who touches it.
- CAS number
- 3486-35-9
- Form
- Solid
- Storage class
- General
- Signal word
- Warning
- Usual EWC code
- 16 05 06*
Hazardous to the environment
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as general stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Because it is a carbonate, acids are the obvious partner to keep it from. Any acid in the prep room will make it fizz and give off gas, so the jar should sit on a general shelf well away from the acid store, and a leaking bottle above it is the sort of accident worth planning around. Otherwise the storage is ordinary: a dry, labelled, tightly closed container, kept off the floor and away from the washing-up area, where a spill must never be allowed to reach a drain. Powder from a school science cupboard often sits in a plastic jar that has been refilled or topped up, so make sure the label still names the contents and carries a date of receipt.
How to tell it has deteriorated
Start with the container and its label, since that is where most of the evidence is. A powder jar that has been opened many times can show a dusty residue on the thread, a cap that no longer turns freely and a label that has been rubbed or stained until the name is hard to read. Inside, look for hard lumps or a crust where damp air has reached the powder. Zinc carbonate itself gives few striking visible signs with age, so do not expect colour changes or fumes. If the label has gone, or the jar has been refilled from something else, treat the contents as unidentified until that is cleared up.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a non-regulated or low hazard laboratory pack with compatible chemicals.
Before asking for a collection, write down what is actually in the container, its size and whether the label is still readable, because an unlabelled white powder is harder to place than a clear one. Zinc carbonate is classified under aquatic hazard statements, so it must never be washed to a drain or put out with ordinary waste, and nobody should try to react it with acid to make it disappear. A laboratory pack uses 16 05 06* and discarded inorganic stock outside a laboratory pack uses 16 05 07*. The powder is grouped away from acids in a compatible pack and goes for specialist collection.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Common quantities we collect
Usually held as: powder.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H400 Very toxic to aquatic life.
- H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
- P273 Avoid release to the environment.
- P391 Collect spillage.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
What should zinc carbonate be stored away from?
Acids, because a carbonate reacts with them and gives off gas. Keep the jar on a general shelf, away from the acid store and any bottle that could leak above it.
Is zinc carbonate classified as hazardous waste?
Yes. It is classified as very toxic to aquatic life, with long lasting effects also listed, so surplus stock is hazardous waste. It needs specialist collection and an accurate description.
Our powder jar has no readable label. What now?
Do not guess from its appearance. Keep it closed, record where it was found and what it might be, and send an enquiry so it can be assessed before it is packed with other stock.
Does it give off warning signs as it ages?
Few. Look at the lid, thread and label for dust, crust or damage, and at the powder for lumps. A clean jar with a clear label and a hard lump or two is still waste for collection, not something to break up.
Related chemicals
Search the chemical database- 1,1,1-TrichloroethaneCAS 71-55-6General
- 1-NaphtholCAS 90-15-3General
- 2-NaphtholCAS 135-19-3General
- 3,3',5,5'-TetramethylbenzidineCAS 54827-17-7General
- 4-NitrophenolCAS 100-02-7General
- AcetophenoneCAS 98-86-2General