Antimony(III) chloride (CAS 10025-91-9): storage and disposal
Antimony trichloride is a corrosive solid that mostly survives as legacy stock in school, college and university stores. It causes severe skin burns and eye damage and is toxic to aquatic life with long lasting effects. Moist air attacks it, which is why an old jar can look much worse than the paperwork suggests.
- CAS number
- 10025-91-9
- Form
- Solid
- Storage class
- Corrosive
- Signal word
- Danger
- Usual EWC code
- 16 05 06*
Corrosive
Hazardous to the environment
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as corrosive stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
Moisture is the first thing to keep away from this solid, because it fumes in damp air and gives off hydrochloric acid mist. Beyond that, it must be separated from oxidisers, which can react with corrosive stock and release heat or fumes, and from solvent cabinets, where a leak could break down the containers and feed a fire. Put it on a resistant tray low down in a ventilated corrosive store, with the lid tight and the jar standing inside a second container. In a school prep room that means a shelf of its own, not a place among the salts. Check metal shelf brackets for rust spotting.
How to tell it has deteriorated
Look at the container before the contents. A jar that is sound has a clean cap, a legible label and crystals that are loose and dry. A jar that has taken in moist air shows wet or sticky lumps, white powder around the lid and mist escaping when it is touched. The white deposit is what the solid becomes when water gets at it. Corroded cap liners, stained or peeling labels and rusty shelves beneath the jar point to long term leakage of fumes. A lid that will not turn should not be forced. Record what you see, leave the jar closed and note how long it has sat there.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a corrosive other laboratory pack with compatible chemicals.
Collection is arranged as a specialist job, with the jar travelling as UN 1733 under waste code 16 05 06* when it is packed in a lab pack. Where it is simply a discarded inorganic chemical outside one, the code is 16 05 07*. Because it reacts with moisture, the packers keep it away from water bearing items, and your description of the cap and crust helps them plan that. Pouring it down a drain is not an option, nor is using a bin or skip, and nobody on site should try to neutralise it. Its harm to aquatic life is the reason for that.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Do not store with
- FlammableA leak of corrosive stock can break down flammable containers and feed a fire.
- OxidiserCorrosive stock can react with oxidisers, releasing heat or fumes.
Named chemicals to keep apart
- AcetoneA leak of corrosive stock can break down flammable containers and feed a fire.
- Calcium hypochloriteCorrosive stock can react with oxidisers, releasing heat or fumes.
- EthanolA leak of corrosive stock can break down flammable containers and feed a fire.
- HexaneA leak of corrosive stock can break down flammable containers and feed a fire.
- Hydrogen peroxideCorrosive stock can react with oxidisers, releasing heat or fumes.
- MethanolA leak of corrosive stock can break down flammable containers and feed a fire.
- Potassium nitrateCorrosive stock can react with oxidisers, releasing heat or fumes.
- Potassium permanganateCorrosive stock can react with oxidisers, releasing heat or fumes.
Show 1 more
- TolueneA leak of corrosive stock can break down flammable containers and feed a fire.
Common quantities we collect
Usually held as: legacy stock.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H314 Causes severe skin burns and eye damage.
- H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
- P260 Do not breathe dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
- P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316 Get emergency medical help immediately.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P363 Wash contaminated clothing before reuse.
- P391 Collect spillage.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why has the powder around the lid of our antimony trichloride jar turned white?
Moist air reaching the solid is the usual cause. Leave the jar closed, stand it on a tray, and record the crust and any mist when you book collection. Do not scrape the deposit away or try to reseat the lid.
What is the waste code for old antimony trichloride from a school lab?
It is 16 05 06* when the jar is packed in a lab pack, or 16 05 07* as a discarded inorganic chemical outside one. The collection team confirms which applies from the description you give at booking.
Is it acceptable to keep it next to other chlorides on the shelf?
Keeping it among dry salts is not the problem. The issues are corrosive fumes attacking neighbours and the stock being near oxidisers or solvents. Give it a separate tray in the corrosive store and keep it dry.
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