Cerium(IV) sulfate (CAS 13590-82-4): storage and disposal
Ceric sulfate is the orange to yellow solid that sits with the redox titration reagents in college and university teaching stores, and sometimes in school prep rooms. It causes severe skin burns and eye damage and is very toxic to aquatic life with long lasting effects. The second hazard matters most at disposal, because it rules out every local route.
- CAS number
- 13590-82-4
- Form
- Solid
- Storage class
- Corrosive
- Signal word
- Danger
- Usual EWC code
- 16 05 06*
Corrosive
Hazardous to the environment
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as corrosive stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
In a school or college prep room ceric sulfate tends to be filed with the titration reagents on an open general shelf, which is the wrong home for a corrosive solid that burns skin. Give it a resistant tray low down in a ventilated corrosive store. In chemistry it acts as a strong oxidant, so keep it clear of organic reagents, paper packaging and anything that can give up electrons, and apart from other oxidisers. Solvent cabinets are a poor neighbour too, since a leak could attack their containers. Because of the aquatic classification, any spill needs absorbing and containing locally and never washing towards a drain.
How to tell it has deteriorated
A good jar holds a dry, free flowing solid in a yellow to orange shade. Few chemistry specific changes show up on the shelf, so the container is the better guide. Lumps, a damp patch at the base or crust around the neck suggest moisture has been drawn in. Corroded caps, cracked containers, stained labels and damage to the shelf beneath all point to leakage over time. Stock that has changed shade noticeably, or that has been topped up from other jars, is recorded as such. Nobody should open a suspect jar to look closer. Note the condition and let the collection team see it as it stands.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a corrosive other laboratory pack with compatible chemicals.
Specialist collection is how this solid leaves the site, grouped with other compatible solids in a lab pack and written up under waste code 16 05 06*. A jar travelling as a discarded inorganic chemical outside a lab pack carries 16 05 07* instead. What helps the packer is a note of the orange colour, the amount left and whether the cap is corroded. Its effect on aquatic life is why no residue, however small, may be sent down a drain. It does not go in a bin or skip, and nobody on site should try to treat or reduce it.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Do not store with
- FlammableA leak of corrosive stock can break down flammable containers and feed a fire.
- OxidiserCorrosive stock can react with oxidisers, releasing heat or fumes.
Named chemicals to keep apart
- AcetoneA leak of corrosive stock can break down flammable containers and feed a fire.
- Calcium hypochloriteCorrosive stock can react with oxidisers, releasing heat or fumes.
- EthanolA leak of corrosive stock can break down flammable containers and feed a fire.
- HexaneA leak of corrosive stock can break down flammable containers and feed a fire.
- Hydrogen peroxideCorrosive stock can react with oxidisers, releasing heat or fumes.
- MethanolA leak of corrosive stock can break down flammable containers and feed a fire.
- Potassium nitrateCorrosive stock can react with oxidisers, releasing heat or fumes.
- Potassium permanganateCorrosive stock can react with oxidisers, releasing heat or fumes.
Show 1 more
- TolueneA leak of corrosive stock can break down flammable containers and feed a fire.
Common quantities we collect
Usually held as: solid.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H314 Causes severe skin burns and eye damage.
- H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
- P260 Do not breathe dust, fume, gas, mist, vapours or spray.
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P271 Use only outdoors or in a well-ventilated area.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316 Get emergency medical help immediately.
- P317 Get medical help.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P363 Wash contaminated clothing before reuse.
- P391 Collect spillage.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why is ceric sulfate kept away from organic reagents in the prep room?
Cerium in this form is a strong oxidant and can react with organic material, releasing heat or fumes. A separate tray in the corrosive store, away from solvents, paper and plastic packaging, removes that risk.
A little solution is left in a beaker after a titration. Can it be rinsed away?
No. The classification is very toxic to aquatic life with long lasting effects, so residues do not go to a drain. Follow your site procedure for labelled aqueous residues and book specialist collection for stock jars.
How long can an opened jar stay on the shelf?
There is no fixed limit for this solid. It stays acceptable while the cap is sound, the contents are dry and the label reads clearly. Date it on arrival, check it at every stock take and book collection if the container starts to fail.
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