Calcium nitrate (CAS 10124-37-5): storage and disposal
Calcium nitrate is held in school, college and university stores almost always as the tetrahydrate, a white granular solid. It is classified as an oxidiser that may intensify fire, and it is harmful if swallowed, irritating to skin and a cause of serious eye damage. Because it draws water from the air and sits next to combustible materials if shelved carelessly, the store it lives in matters as much as the bottle.
- CAS number
- 10124-37-5
- Form
- Solid
- Storage class
- Oxidiser
- Signal word
- Danger
- Usual EWC code, laboratory stock
- 16 05 06*
Oxidising
Corrosive
Harmful or irritant
What to do this week
- Without moving anything that looks damaged, check the label is readable and write down the opened date if it is not already there.
- Check it is stored as oxidiser stock, and apart from anything listed under "Do not store with" on this page. If nothing is listed, that does not prove it is safe with everything.
- If you no longer need it, add it to your disposal list so it can be included in a collection.
Safe storage in a school or lab
The tetrahydrate usually arrives in a plastic or glass jar with a screw cap, and the cap is the weak point because the salt draws moisture from the air. Shelve it in the oxidiser section on non-combustible shelving, apart from flammable, organic and reducing stock. Paper labels, cardboard trays and wooden shelf liners are the combustible items most often found underneath it, and they should go. Keep the jar tightly closed after each use and dated on arrival. A part-used jar from a practical on thermal decomposition or solubility is better kept in its own labelled space than left on the open bench shelf.
How to tell it has deteriorated
Free-flowing white granules are what to expect. The salt takes up water readily, so look for granules that have fused into a cake, a damp film at the bottom of the jar and wet staining on the shelf under it. A cap that has corroded or stuck, and a label that has been attacked by seepage, show that liquid has escaped. Because it is an oxidiser, wet stock that has touched paper, wood or dust is a bigger concern than the same wet stock in a clean tub. Brown staining on a nearby cardboard tray may indicate contact between the oxidiser and combustible material. Do not disturb suspected contaminated stock. Record what is visible and arrange specialist assessment. Note the date of receipt if the jar is undated.
How it is disposed of
We arrange this by specialist collection. We do not publish a drain or general waste route for any chemical. It is normally packed in an oxidising laboratory pack with compatible chemicals.
Leave as a closed jar in the oxidiser group and expect the collection team to keep it away from organic and combustible stock in the pack. It is normally classified as hazardous waste, with 16 05 06* as the usual entry in a lab pack and 16 05 07* where it is a discarded inorganic chemical outside one, though the producer classifies the waste. What makes it awkward is damp: a jar with a caked or wet base needs describing as such, and should travel upright with its cap secure. Do not put it into a sink, a drain, a general waste bin or a skip, and do not try to dry, dilute or neutralise it. Record the form, which is normally the tetrahydrate, and roughly how much remains.
| Usual EWC code, laboratory stock | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Usually classed as hazardous waste | Yes |
The code depends on where the waste came from and what it contains, and classifying it is the producer's duty. Use the waste code finder to see why.
Do not store with
- FlammableOxidisers can ignite flammable materials or make a fire far more intense.
- AcidMany oxidisers release toxic gas or become unstable in contact with acid.
- AlkaliSome oxidisers react strongly with alkalis, and ammonia based stock is especially at risk.
- ToxicToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
- CorrosiveCorrosive stock can react with oxidisers, releasing heat or fumes.
Named chemicals to keep apart
- Acetic acidMany oxidisers release toxic gas or become unstable in contact with acid.
- AcetoneOxidisers can ignite flammable materials or make a fire far more intense.
- Ammonia solutionSome oxidisers react strongly with alkalis, and ammonia based stock is especially at risk.
- EthanolOxidisers can ignite flammable materials or make a fire far more intense.
- FormalinToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
- HexaneOxidisers can ignite flammable materials or make a fire far more intense.
- Hydrochloric acidMany oxidisers release toxic gas or become unstable in contact with acid.
- Mercury(II) chlorideToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
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- MethanolOxidisers can ignite flammable materials or make a fire far more intense.
- Nitric acidMany oxidisers release toxic gas or become unstable in contact with acid.
- Potassium hydroxideSome oxidisers react strongly with alkalis, and ammonia based stock is especially at risk.
- Sodium cyanideToxic and oxidising stock are stored apart. A reaction could release toxic vapours.
- Sodium hydroxideSome oxidisers react strongly with alkalis, and ammonia based stock is especially at risk.
- Sulfuric acidMany oxidisers release toxic gas or become unstable in contact with acid.
- Thionyl chlorideCorrosive stock can react with oxidisers, releasing heat or fumes.
- TolueneOxidisers can ignite flammable materials or make a fire far more intense.
- Zinc chlorideCorrosive stock can react with oxidisers, releasing heat or fumes.
Common quantities
Usually held as: tetrahydrate.
Tell us the container size and how many you hold. An estimate is enough to start with, and some items cannot be priced until someone has looked at them.
Where it is commonly held
Hazard statements
- H272 May intensify fire; oxidiser.
- H302 Harmful if swallowed.
- H315 Causes skin irritation.
- H318 Causes serious eye damage.
Precautionary statements
- P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P220 Keep away from clothing and other combustible materials.
- P234 Keep only in original packaging.
- P260 Do not breathe dust, fume, gas, mist, vapours or spray.
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316 Get emergency medical help immediately.
- P317 Get medical help.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P363 Wash contaminated clothing before reuse.
- P370+P378 In case of fire: Use suitable extinguishing media to extinguish.
- P390 Absorb spillage to prevent material damage.
- P405 Store locked up.
- P406 Store in corrosive resistant container with a resistant inner liner.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why has our calcium nitrate turned into a damp lump?
It takes water from the air, so a loose cap lets it cake and then go wet. That is characteristic of the salt. Keep the jar closed and away from paper and organic stock, and put it forward for collection described as damp.
What can it sit next to on the shelf?
Other oxidisers, on non-combustible shelving. Keep it apart from flammable, organic and reducing materials, and take away cardboard or wooden liners beneath it. It is an oxidiser that may intensify fire, so combustible neighbours are the main concern.
Can we collect a part-used jar of tetrahydrate?
Yes. Part-used jars go through specialist collection as readily as full ones. Keep the cap tight, label the form as tetrahydrate and give the approximate amount left. Note any caking so it is described honestly.
Related chemicals
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