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Chemical collection and stock control for UK schools, universities and hospitals

Zinc chloride (CAS 7646-85-7): storage and disposal

Few solids misbehave on a shelf like zinc chloride. School and college prep rooms hold it as a white solid for demonstrations, and histology staff keep it for staining and fixing work. It is classified as causing severe skin burns and eye damage, is harmful if swallowed and very toxic to aquatic life, and that corrosive character sets the storage and collection rules.

CAS number
7646-85-7
Form
Solid
Storage class
Corrosive
Signal word
Danger
Usual EWC code
16 05 06*
  • Corrosive pictogramCorrosive
  • Harmful or irritant pictogramHarmful or irritant
  • Hazardous to the environment pictogramHazardous to the environment

What to do this week

  1. Check the label is readable and write down the opened date if it is not already there.
  2. Check it is stored as corrosive stock and apart from the items listed under "Do not store with".
  3. If you no longer need it, add it to your disposal list so it goes on the next collection.

Safe storage in a school or lab

Corrosive stock belongs low down, on a resistant tray, in a ventilated corrosive store. This solid draws water out of the air so readily that a loosely closed bottle will slowly turn into a damp mass, so the cap matters more here than for most salts. Keep it away from the solvent cabinet and from the oxidiser shelf, because a leak of corrosive stock can attack containers and a spill beside oxidisers can give off heat or fumes. In a histology room it should not sit at bench height beside fixatives or stains, where a splash would meet skin or eyes. Check that the cap lining is intact and that the tray beneath is dry, and record the date opened on the label.

How to tell it has deteriorated

A technician will see the crystals sticking to each other first. Zinc chloride is strongly water-attracting, so an old bottle often holds a solid cake, a paste or even a puddle of liquid at the base where the powder used to be. Look at the neck and cap for crusting and for corrosion of any metal liner, and at the shelf under the bottle for staining or a damp ring. Fumes on opening, a cracked bottle or a label that has peeled in the wet are all reasons to stop handling it. A once free-flowing solid that now needs chiselling out has changed condition, and it should be described that way on any paperwork.

How it must be disposed of

By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a corrosive other laboratory pack with compatible chemicals.

The code on the paperwork matters for this one. A laboratory pack uses 16 05 06*, while discarded inorganic chemical stock outside a laboratory pack is 16 05 07*, and a human healthcare setting such as a hospital histology lab uses 18 01 06*. Because it is classified as very toxic to aquatic life it must never go down a drain, and nobody should try to dry out or dilute a wet bottle before collection. Leave a caked or leaking container in a second sealed container on a tray, state on the record that it is damp, and book a specialist collection. UN 2331 applies to the carriage.

Waste codes and transport details for Zinc chloride
EWC code, laboratory chemicals16 05 06*
Discarded inorganic chemical, not a laboratory pack16 05 07*
Human healthcare setting18 01 06*
Hazardous wasteYes

The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.

Do not store with

  • FlammableA leak of corrosive stock can break down flammable containers and feed a fire.
  • OxidiserCorrosive stock can react with oxidisers, releasing heat or fumes.

Named chemicals to keep apart

  • AcetoneA leak of corrosive stock can break down flammable containers and feed a fire.
  • Calcium hypochloriteCorrosive stock can react with oxidisers, releasing heat or fumes.
  • EthanolA leak of corrosive stock can break down flammable containers and feed a fire.
  • HexaneA leak of corrosive stock can break down flammable containers and feed a fire.
  • Hydrogen peroxideCorrosive stock can react with oxidisers, releasing heat or fumes.
  • MethanolA leak of corrosive stock can break down flammable containers and feed a fire.
  • Potassium nitrateCorrosive stock can react with oxidisers, releasing heat or fumes.
  • Potassium permanganateCorrosive stock can react with oxidisers, releasing heat or fumes.
Show 1 more
  • TolueneA leak of corrosive stock can break down flammable containers and feed a fire.

Common quantities we collect

Usually held as: solid.

Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.

Where it is commonly held

Hazard statements

  • H302 Harmful if swallowed.
  • H314 Causes severe skin burns and eye damage.
  • H335 May cause respiratory irritation.
  • H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
  • P260 Do not breathe dust, fume, gas, mist, vapours or spray.
  • P264 Wash hands and exposed skin thoroughly after handling.
  • P270 Do not eat, drink or smoke when using this product.
  • P273 Avoid release to the environment.
  • P280 Wear protective gloves, protective clothing, eye protection and face protection.
  • P301+P317 IF SWALLOWED: Get medical help.
  • P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
  • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P316 Get emergency medical help immediately.
  • P321 Specific treatment (see supplemental first aid instruction on this label).
  • P330 Rinse mouth.
  • P363 Wash contaminated clothing before reuse.
  • P391 Collect spillage.
  • P405 Store locked up.
  • P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
  • P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
  • P271 Use only outdoors or in a well-ventilated area.
  • P317 Get medical help.
  • P319 Get medical help if you feel unwell.
  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Substance as classified, dilutions may differ.

Questions

Why has our zinc chloride turned into a wet lump?

It takes water from the air very readily, so a cap that has not been closed fully will let it cake, then turn pasty or liquid. The stock is still corrosive. Keep it in its container, on a tray, and arrange collection instead of scraping it out.

Which waste code should a histology lab use?

A human healthcare setting uses 18 01 06*. A school or university laboratory pack uses 16 05 06*, and discarded stock outside a lab pack is 16 05 07*. Say which applies when you request the collection.

Can we rinse out the empty bottle in the prep room?

No. Rinsings must never go down a drain. Zinc chloride is very toxic to aquatic life, and residue in a bottle counts as part of the waste. Keep the cap on and let the collection take the container as it stands.

How should an old or cracked bottle be stored while waiting for collection?

Stand it on a resistant tray inside a second sealed container in the corrosive store, away from oxidisers and solvents. Do not try to repair the cap or tip the contents into a fresh bottle.

Guidance only. Check your own risk assessment and your supplier's safety data sheet.

Hazard data source: PubChem GHS Classification, retrieved 31 Oct 2026. Formula Cl2Zn. EC number 231-592-0.

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