Sodium dodecyl sulfate (CAS 151-21-3): storage and disposal
Sodium dodecyl sulfate is the foaming detergent salt found in school prep rooms, college and university labs and pathology departments, held as a white powder or as a 10% solution. The powder is classified as a flammable solid that irritates skin and airways and can seriously damage eyes. Its dust, its habit of foaming and its place on the shelf decide how it is handled and collected.
- CAS number
- 151-21-3
- Form
- Solid
- Storage class
- Flammable
- Signal word
- Danger
- Usual EWC code
- 16 05 06*
Flammable
Corrosive
Harmful or irritant
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as flammable stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
A school prep room usually keeps this as one tub of fine white powder, often shelved with the general salts. The classification says otherwise: it is a flammable solid, so it belongs in a ventilated fire-resistant cabinet, away from ignition sources, oxidisers, acids and corrosives. University and pathology labs also hold a ready made 10% solution, which froths heavily if the bottle is shaken, so keep it upright with the cap firm. Dust is the practical problem. The powder irritates skin and the respiratory tract and can seriously damage eyes, so scoop gently and close the lid straight after each use. Date each tub on arrival, because it tends to be forgotten on a crowded shelf.
How to tell it has deteriorated
A sound tub holds a loose, dry white powder that tips freely. Damp turns it to lumps, and a tub left on a cold windowsill or in a damp cupboard may have set hard around the base. In a bottle of 10% solution, a white cloudy deposit on the bottom after a spell somewhere cold is the detergent coming back out of solution, which is worth recording but is not on its own a sign of failure. Dried froth stuck inside the neck shows that the bottle has been shaken and left. Look as well for a faded label, a crust at the cap, a cracked bottle and a tub with no date of receipt.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a flammable laboratory pack with compatible chemicals.
Packed in a lab pack, this flammable solid is kept apart from oxidisers, acids and corrosives, and a bottle of the 10% solution is grouped separately from the tub of powder rather than combined with it. Waste code 16 05 06* fits a school or university holder, while a hospital pathology lab would use 18 01 06*. Neither the powder nor the solution goes into a sink, a drain, a general waste bin or a skip, however mild it may look, and staff should not try to treat it first. Record the container size, whether it is powder or solution, and any residue on the outside of the pot, since a sticky, powdery exterior makes handling harder for the collection crew.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded organic chemical, not a laboratory pack | 16 05 08* |
| Human healthcare setting | 18 01 06* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Do not store with
- OxidiserOxidisers can ignite flammable materials or make a fire far more intense.
- AcidOxidising acids can ignite flammable materials, and acid fumes attack containers and seals.
- CorrosiveA leak of corrosive stock can break down flammable containers and feed a fire.
Named chemicals to keep apart
- Acetic acidOxidising acids can ignite flammable materials, and acid fumes attack containers and seals.
- Calcium hypochloriteOxidisers can ignite flammable materials or make a fire far more intense.
- Hydrochloric acidOxidising acids can ignite flammable materials, and acid fumes attack containers and seals.
- Hydrogen peroxideOxidisers can ignite flammable materials or make a fire far more intense.
- Nitric acidOxidising acids can ignite flammable materials, and acid fumes attack containers and seals.
- Potassium nitrateOxidisers can ignite flammable materials or make a fire far more intense.
- Potassium permanganateOxidisers can ignite flammable materials or make a fire far more intense.
- Sulfuric acidOxidising acids can ignite flammable materials, and acid fumes attack containers and seals.
Show 2 more
- Thionyl chlorideA leak of corrosive stock can break down flammable containers and feed a fire.
- Zinc chlorideA leak of corrosive stock can break down flammable containers and feed a fire.
Common quantities we collect
Usually held as: solid, 10% solution.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H228 Flammable solid.
- H302 Harmful if swallowed.
- H315 Causes skin irritation.
- H318 Causes serious eye damage.
- H335 May cause respiratory irritation.
- H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
- P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P240 Ground and bond container and receiving equipment.
- P241 Use explosion-proof electrical, ventilating and lighting equipment.
- P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P264+P265 Wash hands and exposed skin thoroughly after handling. Do not touch eyes.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P317 IF SWALLOWED: Get medical help.
- P302+P352 IF ON SKIN: Wash with plenty of water.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317 Get medical help.
- P319 Get medical help if you feel unwell.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P330 Rinse mouth.
- P332+P317 If skin irritation occurs: Get medical help.
- P337+P317 If eye irritation persists: Get medical help.
- P362+P364 Take off contaminated clothing. And wash it before reuse.
- P370+P378 In case of fire: Use suitable extinguishing media to extinguish.
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why is a detergent powder classed as a flammable solid?
The classification lists it as a flammable solid, harmful if swallowed and seriously damaging to eyes, whatever its everyday use. That is why the powder is kept away from ignition sources, oxidisers and acids, and not left with ordinary cleaning supplies.
Does the 10% solution need different handling from the powder?
It is stored upright with the cap tight, away from acids and oxidisers, and it froths if shaken. For collection it is described as a solution and grouped separately from the dry powder, though both follow the same specialist route.
My solution has gone cloudy in the cold. Is it spoiled?
A white deposit after a cold spell is usually the detergent separating out. Note it on the stock record and the label. Do not try to rework it. If the bottle is undated, cracked or leaking, list it for collection instead.
Can a school put small leftover amounts in the bin?
No. It is classified as a flammable solid with several health hazards and harm to aquatic life, so even small amounts go by specialist collection, not into general waste, a sink or a drain.
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