Zinc iodide (CAS 10139-47-6): storage and disposal
Zinc iodide is a corrosive white solid that school, college and university prep rooms hold in small bottles for salt and halide work. It is classified as causing severe skin burns and eye damage. That is the only hazard statement on the record, but it is enough to decide the shelf it sits on and the way it is described for collection.
- CAS number
- 10139-47-6
- Form
- Solid
- Storage class
- Corrosive
- Signal word
- Danger
- Usual EWC code
- 16 05 06*
Corrosive
What to do this week
- Check the label is readable and write down the opened date if it is not already there.
- Check it is stored as corrosive stock and apart from the items listed under "Do not store with".
- If you no longer need it, add it to your disposal list so it goes on the next collection.
Safe storage in a school or lab
The corrosive classification puts this bottle low down, on a resistant tray, in a ventilated corrosive store. It does not belong on the solvent shelf, where a leak could eat into containers and feed a fire, or beside the oxidisers, which can react with corrosive stock and give off heat or fumes. Iodides are also easily oxidised, so a bottle shared with an oxidising shelf is doubly badly placed. Keep light off it as far as a cupboard allows, since an iodide bottle left on a sunny window ledge changes more quickly. Check that the cap seats properly, write the date received on the label, and keep the stock record in step with what is actually on the tray.
How to tell it has deteriorated
Colour is the clue to watch. Iodide salts tend to turn yellow, then brown, as iodine is slowly set free from them by air and light, so a bottle that has gone from white to tan has been standing too long or too bright. The solid also draws moisture, so look for clumping, a damp cake and a wet ring beneath the base. Brown staining on the inside of the cap or on the tray is another sign that iodine vapour or liquid has escaped. A cracked bottle, a perished cap and a label peeled off by damp all need recording. An even white powder in a dry, clean bottle is what normal looks like.
How it must be disposed of
By specialist collection only. It never goes down the drain or into general waste. It is normally packed in a corrosive other laboratory pack with compatible chemicals.
The waste code carries real meaning here. Zinc iodide in a laboratory pack goes under 16 05 06*, and discarded inorganic stock outside a laboratory pack goes under 16 05 07*, so say which one describes your collection. It is a corrosive hazardous waste and the bottle should be collected whole, with the cap taped and the label legible, standing in a tray until the carrier arrives. Never try to dissolve a caked bottle or rinse it out to make it easier to move, and keep it out of drains and bins. Record the brown discolouration or damp if present, and the collector groups the bottle with compatible corrosive stock in a lab pack.
| EWC code, laboratory chemicals | 16 05 06* |
|---|---|
| Discarded inorganic chemical, not a laboratory pack | 16 05 07* |
| Hazardous waste | Yes |
The code depends on where the waste came from and what it is mixed with. Use the waste code finder to see why.
Do not store with
- FlammableA leak of corrosive stock can break down flammable containers and feed a fire.
- OxidiserCorrosive stock can react with oxidisers, releasing heat or fumes.
Named chemicals to keep apart
- AcetoneA leak of corrosive stock can break down flammable containers and feed a fire.
- Calcium hypochloriteCorrosive stock can react with oxidisers, releasing heat or fumes.
- EthanolA leak of corrosive stock can break down flammable containers and feed a fire.
- HexaneA leak of corrosive stock can break down flammable containers and feed a fire.
- Hydrogen peroxideCorrosive stock can react with oxidisers, releasing heat or fumes.
- MethanolA leak of corrosive stock can break down flammable containers and feed a fire.
- Potassium nitrateCorrosive stock can react with oxidisers, releasing heat or fumes.
- Potassium permanganateCorrosive stock can react with oxidisers, releasing heat or fumes.
Show 1 more
- TolueneA leak of corrosive stock can break down flammable containers and feed a fire.
Common quantities we collect
Usually held as: solid.
Part-used bottles and full containers are both fine. Tell us the size and how many, and an estimate is enough for a first price.
Where it is commonly held
Hazard statements
- H314 Causes severe skin burns and eye damage.
Precautionary statements
- P260 Do not breathe dust, fume, gas, mist, vapours or spray.
- P264 Wash hands and exposed skin thoroughly after handling.
- P273 Avoid release to the environment.
- P280 Wear protective gloves, protective clothing, eye protection and face protection.
- P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
- P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316 Get emergency medical help immediately.
- P321 Specific treatment (see supplemental first aid instruction on this label).
- P363 Wash contaminated clothing before reuse.
- P391 Collect spillage.
- P405 Store locked up.
- P501 Dispose of contents and container in accordance with local, regional, national and international regulations.
Substance as classified, dilutions may differ.
Questions
Why has our zinc iodide turned yellow or brown?
Iodide salts slowly release iodine in air and light, which tints the solid and can stain the cap. It is still corrosive stock. Note the colour on the record, keep the cap on and arrange a specialist collection.
Which waste code should we quote for a school prep room?
Stock sent as part of a laboratory pack uses 16 05 06*. Discarded inorganic chemical outside a laboratory pack uses 16 05 07*. Tell the collector which situation applies so the paperwork describes it properly.
Can we store it with our other halide salts?
Not if they sit on an ordinary shelf. Zinc iodide is classified as causing severe skin burns and eye damage, so it goes in the corrosive store low down on a tray, away from oxidisers and solvents.
What do we do with a bottle that has set solid?
Leave it as it is. Do not chip at it or add water. Stand it on a tray in the corrosive store, describe it as caked on the enquiry and wait for collection.
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